Asymmetric Dearomatization of beta-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction | |
Wang SG(王守国)1; Liu XJ(刘喜佳)1; Zhao QC(赵群超)1; Zheng C(郑超)1; Wang SB(王少博)1; You SL(游书力)1 | |
刊名 | Angew. Chem.-Int. Edit. |
2015 | |
卷号 | 54期号:49页码:14929-14932 |
其他题名 | 双功能硫脲催化的Michael反应实现β-萘酚的不对称去芳构化 |
通讯作者 | 游书力 |
英文摘要 | An intermolecular asymmetric dearomatization reaction of beta-naphthols with nitroethylene through a chiralthiourea-catalyzed Michael reaction is described. Enantioen-riched functionalized beta-naphthalenones with an all-carbon quaternary stereogenic center could thus be easily constructed from simple naphthol derivatives in good yields and excellent enantioselectivity (up to 79% yield, 98% ee). |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/anie.201507998 |
语种 | 英语 |
WOS记录号 | WOS:000367723400062 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39683] |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
作者单位 | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.天津化学化工协同创新中心 |
推荐引用方式 GB/T 7714 | Wang SG,Liu XJ,Zhao QC,et al. Asymmetric Dearomatization of beta-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction[J]. Angew. Chem.-Int. Edit.,2015,54(49):14929-14932. |
APA | 王守国,刘喜佳,赵群超,郑超,王少博,&游书力.(2015).Asymmetric Dearomatization of beta-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction.Angew. Chem.-Int. Edit.,54(49),14929-14932. |
MLA | 王守国,et al."Asymmetric Dearomatization of beta-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction".Angew. Chem.-Int. Edit. 54.49(2015):14929-14932. |
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