Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides

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	Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides
	Li DY(李德尧); Wei Y(魏音); Shi M(施敏)
刊名	Eur. J. Org. Chem.
	2015
期号	19 页码:4108-4113
其他题名	金催化的1,3-氧迁移反应: 从炔磺酰胺到炔酰胺
通讯作者	魏音 ; 施敏
英文摘要	The gold-catalyzed 1,3-O-transposition reaction of ynesulfonamides provides a practical synthetic protocol for the synthesis of ynamides under mild conditions. This is the first 1,3-O-transposition example of ynesulfonamides in which a heteroatom is attached to the alkynyl terminal. A plausible mechanism is been proposed on the basis of O-18-labeling and control experiments as well as DFT calculation. By simple treatment, the obtained ynamides can easily be transformed into useful products.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/ejoc.201500604
语种	英语
WOS记录号	WOS:000356870600009
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39611]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所, 金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Li DY,Wei Y,Shi M. Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides[J]. Eur. J. Org. Chem.,2015(19):4108-4113.
APA	李德尧,魏音,&施敏.(2015).Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides.Eur. J. Org. Chem.(19),4108-4113.
MLA	李德尧,et al."Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides".Eur. J. Org. Chem. .19(2015):4108-4113.