Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams

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	Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams
	Wu SZ(吴尚泽)1; Ceng R(曾荣)1; Fu CL(傅春玲)1; Yu YH(余亦华)1; Zhang X(张雪)1; Ma SM(麻生明)1
刊名	Chem. Sci.
	2015
卷号	6 期号:4 页码:2275-2285
其他题名	铑催化的通过C-H键活化合成八元内酰胺的方法
通讯作者	张雪 ; 麻生明
英文摘要	A Rh(III) catalyzed formal [4 + 2 + 2] cyclization of N-pivaloyloxybenzamides 1 with 1,6-allene-enes 2 by C-H functionalization is reported. The reactions occur at room temperature and are compatible with air and moisture with a tolerance of many synthetically useful functional groups. The follow-up modifications of the products have been demonstrated. After careful mechanistic studies and DFT calculation, a reaction mechanism was proposed.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1039/c5sc00092k
语种	英语
WOS记录号	WOS:000351412800016
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39584]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.浙江大学 2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Wu SZ,Ceng R,Fu CL,et al. Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams[J]. Chem. Sci.,2015,6(4):2275-2285.
APA	吴尚泽,曾荣,傅春玲,余亦华,张雪,&麻生明.(2015).Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams.Chem. Sci.,6(4),2275-2285.
MLA	吴尚泽,et al."Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams".Chem. Sci. 6.4(2015):2275-2285.