Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles
	Zhao YZ(赵允州); Yang HB(杨海斌); Tang XY(唐翔鹰); Shi M(施敏)
刊名	Chem.-Eur. J.
	2015
卷号	21 期号:9 页码:3562-3566
其他题名	铑(II)催化的氮杂三元环和三氮唑的[3+2]环加成反应
通讯作者	唐翔鹰 ; 施敏
英文摘要	Rh-II-catalyzed intermolecular [3+2] cycloaddition of 2H-azirines with N-sulfonyl-1,2,3-triazoles is disclosed, in which a series of fully functionalized pyrroles is produced via rhodium azavinyl carbene intermediates. A distinct feature of this reaction is that the azavinyl carbene serves as a [2C] equivalent, instead of as [1C] or aza-[3C] synthons, which have been reported previously in cyclopropanations and [3+n] cycloadditions. Moreover, this methodology has also been successfully applied in the total synthesis of URB447 as well as the formal synthesis of Atorvastatin (Lipitor).
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/chem.201406460
语种	英语
WOS记录号	WOS:000350116200010
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39580]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所, 金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Zhao YZ,Yang HB,Tang XY,et al. Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles[J]. Chem.-Eur. J.,2015,21(9):3562-3566.
APA	赵允州,杨海斌,唐翔鹰,&施敏.(2015).Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles.Chem.-Eur. J.,21(9),3562-3566.
MLA	赵允州,et al."Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles".Chem.-Eur. J. 21.9(2015):3562-3566.