Study on the accelerated Gutknecht selfcyclocondensation of amino-sugars under atmospheric pressure chemical ionization conditions

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	Study on the accelerated Gutknecht selfcyclocondensation of amino-sugars under atmospheric pressure chemical ionization conditions
	Wang HY(王昊阳)1; Zhang JT(张骏婷)1; Sun SH(孙世豪)1; Zhang SS(张曙盛)1; Zhang F(张芳)1; Zhu H(朱晖)1; Guo YL(郭寅龙)1
刊名	RSC Adv.
	2015
卷号	5 期号:127 页码:105079-105083
其他题名	大气压化学电离条件下氨基糖加速Gutknecht自缩合的研究
通讯作者	王昊阳 ; 郭寅龙
英文摘要	An unexpected gas phase Gutknecht self-condensation of D-glucosamine hydrochloride to 2,5-deoxyfructosazine (2,5-DOF) in atmospheric pressure chemical ionization mass spectrometry (APCI-MS) was described. Mechanistic studies indicated that the thermospray conditions in APCI largely accelerate the irreversible Gutknecht self-cyclocondensation reaction of amino-sugars. Our observations provide a promising clue for a new borate-free synthetic method of 2,5-DOF by mimicking the APCI conditions.
学科主题	分析化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1039/c5ra22331h
语种	英语
WOS记录号	WOS:000366865900052
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39698]
专题	上海有机化学研究所_分析化学研究室
作者单位	1.中科院上海有机化学研究所 2.中国烟草总公司郑州烟草研究院
推荐引用方式 GB/T 7714	Wang HY,Zhang JT,Sun SH,et al. Study on the accelerated Gutknecht selfcyclocondensation of amino-sugars under atmospheric pressure chemical ionization conditions[J]. RSC Adv.,2015,5(127):105079-105083.
APA	王昊阳.,张骏婷.,孙世豪.,张曙盛.,张芳.,...&郭寅龙.(2015).Study on the accelerated Gutknecht selfcyclocondensation of amino-sugars under atmospheric pressure chemical ionization conditions.RSC Adv.,5(127),105079-105083.
MLA	王昊阳,et al."Study on the accelerated Gutknecht selfcyclocondensation of amino-sugars under atmospheric pressure chemical ionization conditions".RSC Adv. 5.127(2015):105079-105083.