Micellization of long-chain ionic liquids in deep eutectic solvents

CORC > 化学研究所 > 中国科学院化学研究所 > 胶体、界面与化学热力学实验室

	Micellization of long-chain ionic liquids in deep eutectic solvents
	Tan, Xiuniang 1,2; Zhang, Jianling 1; Luo, Tian 1,2; Sang, Xinxin 1; Liu, Chengcheng 1; Zhang, Bingxing 1; Peng, Li 1; Li, Wei 2; Han, Buxing 1
刊名	SOFT MATTER
	2016
卷号	12 期号:24 页码:5297-5303
英文摘要	The aggregation behavior of the ionic liquid (IL) 1-alkyl-3-methylimidazolium chloride with different alkyl chain lengths in a deep eutectic solvent (DES, composed of choline chloride and glycerol in a 1 : 2 mole ratio) was studied for the first time. The critical micellar concentration, micellar size and intermolecular interactions in IL/DES solutions were investigated by different techniques including the fluorescence probe technique, small angle X-ray scattering and Fourier transform infrared spectroscopy. The solvophobic effect dominates the micellization of C(n)mimCl in DES and the intermolecular hydrogen-bond interaction plays a positive role to promote micelle formation. The micellar solutions were utilized for the synthesis of the water-unstable metal-organic framework Cu-3(BTC)(2) (BTC = 1,3,5-benzenetricarboxylate) at room temperature. X-Ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption-desorption isotherms confirm the formation of crystalline Cu-3(BTC)(2) nanocrystals with mesoporous structures. The morphologies and porosity properties of Cu-3(BTC)(2) nanocrystals can be modulated by varying the concentration of C(n)mimCl.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35564]
专题	化学研究所_胶体、界面与化学热力学实验室
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Colloid & Interface & Thermodynam, Beijing 100190, Peoples R China 2.Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China
推荐引用方式 GB/T 7714	Tan, Xiuniang,Zhang, Jianling,Luo, Tian,et al. Micellization of long-chain ionic liquids in deep eutectic solvents[J]. SOFT MATTER,2016,12(24):5297-5303.
APA	Tan, Xiuniang.,Zhang, Jianling.,Luo, Tian.,Sang, Xinxin.,Liu, Chengcheng.,...&Han, Buxing.(2016).Micellization of long-chain ionic liquids in deep eutectic solvents.SOFT MATTER,12(24),5297-5303.
MLA	Tan, Xiuniang,et al."Micellization of long-chain ionic liquids in deep eutectic solvents".SOFT MATTER 12.24(2016):5297-5303.