Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds

	Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds
	Ren, Xiaoyu; Du, Haifeng
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2016-01-27
卷号	138 期号:3 页码:810-813
英文摘要	A highly enantioselective hydrosilylation of 1,2-dicarbonyl compounds was successfully realized for the first time utilizing the combination of tricyclohexylphosphine and chiral alkenylborane derived in situ from diyne as a frustrated Lewis pair catalyst. A variety of optically active a-hydroxy ketones and esters were obtained in 52-98% yields with 86-99% ees.
收录类别	SCI ; IC ; CCR
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35807]
专题	化学研究所_分子识别与功能实验室
作者单位	Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Ren, Xiaoyu,Du, Haifeng. Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2016,138(3):810-813.
APA	Ren, Xiaoyu,&Du, Haifeng.(2016).Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,138(3),810-813.
MLA	Ren, Xiaoyu,et al."Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 138.3(2016):810-813.