The Electrochemistry with Lithium versus Sodium of Selenium Confined To Slit Micropores in Carbon

CORC > 化学研究所 > 中国科学院化学研究所 > 分子纳米结构与纳米技术实验室

	The Electrochemistry with Lithium versus Sodium of Selenium Confined To Slit Micropores in Carbon
	Xin, Sen 1; Yu, Le 2,3; You, Ya 2,3; Cong, Huai-Ping 1; Yin, Ya-Xia 2,3; Du, Xue-Li 1; Guo, Yu-Guo 2,3; Yu, Shu-Hong 6; Cui, Yi 7,8; Goodenough, John B.4,5
刊名	NANO LETTERS
	2016-07-01
卷号	16 期号:7 页码:4560-4568
关键词	Energy storage metal-selenium battery microporous carbon confined selenium chain selenium electrochemistry
英文摘要	Substitution of selenium for sulfur in the cathode of a rechargeable battery containing S-s molecules in microporous slits in carbon allows a better characterization of the electrochemical reactions that occur. Paired with a metallic lithium anode, the Se-x chains are converted to Li2Se in a single-step reaction. With a sodium anode, a sequential chemical reaction is characterized by a continuous chain shortening of Se-x upon initial discharge before completing the reduction to Na2Se; on charge, the reconstituted Se-x molecules retain a smaller x value than the original Se-x chain molecule. In both cases, the Se molecules remain almost completely confined to the micropore slits to give a long cycle life.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35600]
专题	化学研究所_分子纳米结构与纳米技术实验室
作者单位	1.Hefei Univ Technol, Sch Chem & Chem Engn, Hefei 230009, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 3.BNLMS, Beijing 100190, Peoples R China 4.Univ Texas Austin, Mat Sci & Engn Program, 1 Univ Stn,C2201, Austin, TX 78712 USA 5.Univ Texas Austin, Texas Mat Inst, 1 Univ Stn,C2201, Austin, TX 78712 USA 6.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Div Nanomat & Chem, Dept Chem, Hefei 230026, Anhui, Peoples R China 7.Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA 8.Stanford Univ, Dept Chem, Stanford, CA 94305 USA
推荐引用方式 GB/T 7714	Xin, Sen,Yu, Le,You, Ya,et al. The Electrochemistry with Lithium versus Sodium of Selenium Confined To Slit Micropores in Carbon[J]. NANO LETTERS,2016,16(7):4560-4568.
APA	Xin, Sen.,Yu, Le.,You, Ya.,Cong, Huai-Ping.,Yin, Ya-Xia.,...&Goodenough, John B..(2016).The Electrochemistry with Lithium versus Sodium of Selenium Confined To Slit Micropores in Carbon.NANO LETTERS,16(7),4560-4568.
MLA	Xin, Sen,et al."The Electrochemistry with Lithium versus Sodium of Selenium Confined To Slit Micropores in Carbon".NANO LETTERS 16.7(2016):4560-4568.