M2Ca3B16O28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	M2Ca3B16O28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers
	Zhang, XY (Zhang, Xiangyu); Li, DN (Li, Danni); Wu, HP (Wu, Hongping); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
刊名	RSC ADVANCES
	2016
卷号	6 期号:17 页码:14205-14210
通讯作者	Wu, HP
英文摘要	Two isostructural alkali calcium borates, M2Ca3B16O28 (M = Rb, Cs) have been successfully synthesized by the flux method. The two compounds crystallize in the monoclinic space group C2/c (no. 15) and feature three-dimensional open-framework layers. The M+ (M = Rb, Cs) cations occupy in-layer three-dimensional micro-pores, and the Ca2+ cations bridge the layers to form the three-dimensional network. Based on the structure analysis, it is found that M2Ca3B16O28 (M = Rb, Cs) compounds have a similar structure to that of Sr2Be2B2O7. In addition, spectroscopic properties and first-principle calculations have been carried out on the title compounds.
收录类别	SCI
WOS记录号	WOS:000369639400074
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/4537]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang, XY ,Li, DN ,Wu, HP ,et al. M2Ca3B16O28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers[J]. RSC ADVANCES,2016,6(17):14205-14210.
APA	Zhang, XY ,Li, DN ,Wu, HP ,Yang, ZH ,&Pan, SL .(2016).M2Ca3B16O28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers.RSC ADVANCES,6(17),14205-14210.
MLA	Zhang, XY ,et al."M2Ca3B16O28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers".RSC ADVANCES 6.17(2016):14205-14210.