Air Cushion Convection Inhibiting Icing of Self-Cleaning Surfaces
Yang, Qin1,2; Luo, Zhuangzhu1; Jiang, Faming1,2; Luo, Yimin1; Tan, Sheng1; Lu ZB(鲁志斌)3; Zhang ZZ(张招柱)3; Liu WM(刘维民)3
刊名ACS Applied Materials and Interfaces
2016
卷号8期号:42页码:29169-29178
关键词superhydrophobic surfaces icing-delay porous structure air cushion convection heat and mass transfer
ISSN号1944-8244
通讯作者Luo, Zhuangzhu
英文摘要

Anti-icing surfaces/interfaces are of considerable importance in various engineering fields under natural freezing environment. Although superhydrophobic self-cleaning surfaces show good anti-icing potentials, promotion of these surfaces in engineering applications seems to enter a “bottleneck” stage. One of the key issues is the intrinsic relationship between superhydrophobicity and icephobicity is unclear, and the dynamic action mechanism of “air cushion” (a key internal factor for superhydrophobicity) on icing suppression was largely ignored. Here we report that icing inhibition (i.e., icing-delay) of self-cleaning surfaces is mainly ascribed to air cushion and its convection. We experimentally found air cushion on the porous self-cleaning coating under vacuum environments and on the water/ice-coating interface at low temperatures. The icing-delay performances of porous self-cleaning surfaces compared with bare substrate, up to 10–40 min under 0 to ∼−4 °C environments close to freezing rain, have been accurately real-time recorded by a novel synergy method including high-speed photography and strain sensing voltage. Based on the experimental results, we innovatively propose a physical model of “air cushion convection inhibiting icing”, which envisages both the static action of trapped air pocket without air flow and dynamic action of air cushion convection. Gibbs free energy of water droplets increased with the entropy of air derived from heat and mass transfer between warmer air underneath water droplets and colder surrounding air, resulting in remarkable ice nucleation delay. Only when air cushion convection disappears can ice nucleation be triggered on suitable Gibbs free energy conditions. The fundamental understanding of air cushion on anti-icing is an important step toward designing optimal anti-icing surfaces for practical engineering application.

学科主题材料科学与物理化学
收录类别SCI
资助信息National Natural ScienceFoundation of China (51575504);National Natural Science Foundation of China (51605466);Chongqing frontier and application basic research project (CSTC2014jcyjA50037)
语种英语
WOS记录号WOS:000386540300101
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/20990]  
专题兰州化学物理研究所_固体润滑国家重点实验室
兰州化学物理研究所_先进润滑与防护材料研究发展中心
作者单位1.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Yang, Qin,Luo, Zhuangzhu,Jiang, Faming,et al. Air Cushion Convection Inhibiting Icing of Self-Cleaning Surfaces[J]. ACS Applied Materials and Interfaces,2016,8(42):29169-29178.
APA Yang, Qin.,Luo, Zhuangzhu.,Jiang, Faming.,Luo, Yimin.,Tan, Sheng.,...&Liu WM.(2016).Air Cushion Convection Inhibiting Icing of Self-Cleaning Surfaces.ACS Applied Materials and Interfaces,8(42),29169-29178.
MLA Yang, Qin,et al."Air Cushion Convection Inhibiting Icing of Self-Cleaning Surfaces".ACS Applied Materials and Interfaces 8.42(2016):29169-29178.
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