Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids

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	Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids
	Zhou H(周慧)1,2; Zhang JL(张金龙)1; Yang HM(杨化萌)1; Xia CG(夏春谷)1 ; Jiang GX(蒋高喜)1
刊名	Organometallics
	2016
卷号	35 期号:19 页码:3406-3412
ISSN号	0276-7333
通讯作者	蒋高喜
英文摘要	An unprecedented rhodium-catalyzed selective cleavage of double alkyl-oxygen bonds of bis/tris(o-alkyloxyphenyl)phosphine has been realized, in which P atom functions as a directing group and simple aryl acids are the methyl group acceptor to provide methyl esters and a quaternary phosphonium salt. The preliminary mechanism was investigated via an ¹⁸O labeling experiment and stoichiometric reaction between a Rh-A crystal and an aromatic acid.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the Hundred Talent Program of Chinese Academy of Sciences (CAS);the Natural Science Foundation of Jiangsu (Grant No. BK20151235)
语种	英语
WOS记录号	WOS:000385209400019
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/21039]
专题	兰州化学物理研究所_OSSO国家重点实验室兰州化学物理研究所_苏州研究院
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys LICP, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhou H,Zhang JL,Yang HM,et al. Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids[J]. Organometallics,2016,35(19):3406-3412.
APA	Zhou H,Zhang JL,Yang HM,Xia CG,&Jiang GX.(2016).Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids.Organometallics,35(19),3406-3412.
MLA	Zhou H,et al."Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids".Organometallics 35.19(2016):3406-3412.