Pd(II)-Catalyzed Pyridine N-Oxides Directed Arylation of Unactivated C-sp(3)-H Bonds
Liu, Jianzhong; Xie, Ying; Zeng, Wei; Lin, Dongen; Deng, Yuanfu; Lu, Xiaoxia
刊名JOURNAL OF ORGANIC CHEMISTRY
2015
卷号80期号:9页码:4618-4626
关键词C-H BONDS PALLADIUM-CATALYZED ARYLATION C(SP(3))-H BONDS INTERMOLECULAR ARYLATION SELECTIVE ALKENYLATION ACTIVATION ACIDS AUXILIARY COPPER SP(2)
通讯作者Zeng, W (reprint author), S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China.
产权排序1
合作状况国内
英文摘要A novel Pd(II)-catalyzed pyridine hi-oxide directed remote arylation of unactivated C-sp(3)-H bonds in aliphatic amides with aryl iodides has been developed. This protocol allows installing various aryl groups at the beta, or gamma-C-sp(3) atom of alkyl carboxylic acid amides. The key palladabicyclic intermediate of this transformation has been identified by HR-MS and H-1 NMR method.
学科主题Chemistry
类目[WOS]Chemistry, Organic
收录类别SCI
语种英语
内容类型期刊论文
源URL[http://210.75.237.14/handle/351003/27586]  
专题成都生物研究所_天然产物研究
推荐引用方式
GB/T 7714
Liu, Jianzhong,Xie, Ying,Zeng, Wei,et al. Pd(II)-Catalyzed Pyridine N-Oxides Directed Arylation of Unactivated C-sp(3)-H Bonds[J]. JOURNAL OF ORGANIC CHEMISTRY,2015,80(9):4618-4626.
APA Liu, Jianzhong,Xie, Ying,Zeng, Wei,Lin, Dongen,Deng, Yuanfu,&Lu, Xiaoxia.(2015).Pd(II)-Catalyzed Pyridine N-Oxides Directed Arylation of Unactivated C-sp(3)-H Bonds.JOURNAL OF ORGANIC CHEMISTRY,80(9),4618-4626.
MLA Liu, Jianzhong,et al."Pd(II)-Catalyzed Pyridine N-Oxides Directed Arylation of Unactivated C-sp(3)-H Bonds".JOURNAL OF ORGANIC CHEMISTRY 80.9(2015):4618-4626.
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