2-氨基-6-乙氧基苯并噻唑类偶氮染料及其金属鏊合物的合成及光学热学性能研究

CORC > 上海光学精密机械研究所 > 中国科学院上海光学精密机械研究所 > 高密度光存储技术实验室

	2-氨基-6-乙氧基苯并噻唑类偶氮染料及其金属鏊合物的合成及光学热学性能研究; Synthesis of 2-(6-ethoxy-2-benzothiazolyazo)-5-diethylaminotrifluoromethane sulfonanilide and study on optical and thermal properties of metal-azo complexes
	陈文忠 ; 吴谊群 ; 顾冬红 ; 干福熹
刊名	功能材料
	2007
卷号	38 期号:5 页码:774
关键词	金属鏊合物 Absorption spectra 吸收光谱 Metal complexes 热学性能 Optical constants 光学常数 Optical disk storage NVD Optical films Refractive index Synthesis (chemical) Thermodynamic properties
ISSN号	1001-9731
其他题名	Synthesis of 2-(6-ethoxy-2-benzothiazolyazo)-5-diethylaminotrifluoromethane sulfonanilide and study on optical and thermal properties of metal-azo complexes
中文摘要	合成了2-（2-氨基-6-乙氧基苯并噻唑基偶氮）-5-（N,N-二乙基氨基）三氟甲基磺酰苯胺偶氮染料（EBTDATFS）及其与乙酸镍、乙酸钴、乙酸铜、乙酸锌等金属盐鏊合的金属鏊合物。通过红外光谱、紫外-可见吸收光谱和MALDI质谱等对染料及其金属鏊合物进行了结构表征;使用旋涂方法在K9玻璃和抛光的单晶硅基片上制备薄膜;研究了镍金属鏊合物的热学性能;使用椭偏仪研究了Ni和Zn鏊合物的光学常数。结果表明：4种金属鏊合物薄膜最大吸收光谱为621-629nm,且长波边吸收峰陡峭;TGA-DSC测试结果表明镍金属鏊; abstract {2-(6-ethoxy-2-benzothiazolyazo)-5-diethylaminotrifluoromethane sulfonanilide and its metal (Ni²⁺, Co²⁺, Cu²⁺, Zn²⁺)-azo complexes were synthesized. Their structures were confirmed by elemental analysis, UV-vis absorption spectra, FT-IR, ¹H-NMR and MALDI-MS. Thin films were prepared on K9 glass and polished single-crystal silicon by spin-coating method. The thermal properties of metal complexes were studied by DSC-TGA. The optical constants (complex refractive index N=n+ik) and thickness of the complex thin films on polished single-crystal silicon substrates in the 350 to 800 nm wavelength region have been investigated on an improved rotating analyzer-polarizer type of scanning ellipsometer. Results indicate that the maximal absorption wavelength of metal-azo complexes locate at 621 to 629 nm. The thermal decomposition temperature of the Ni-azo complex is 325°C with a sharp threshold. High refractive index n and low extinction coefficient k are obtained at the recording wavelength of 650 nm. Metal-azo complexes would be promising recording medium candidate for NVD (next-generation versatile disc) with the Super resolution near field structure (Super-RENS) technology.}
学科主题	光存储
分类号	O631;TN383.1
收录类别	EI
语种	中文
公开日期	2009-09-22 ; 2010-10-12
内容类型	期刊论文
源URL	[http://ir.siom.ac.cn/handle/181231/3991]
专题	上海光学精密机械研究所_高密度光存储技术实验室
推荐引用方式 GB/T 7714	陈文忠,吴谊群,顾冬红,等. 2-氨基-6-乙氧基苯并噻唑类偶氮染料及其金属鏊合物的合成及光学热学性能研究, Synthesis of 2-(6-ethoxy-2-benzothiazolyazo)-5-diethylaminotrifluoromethane sulfonanilide and study on optical and thermal properties of metal-azo complexes[J]. 功能材料,2007,38(5):774, 777.
APA	陈文忠,吴谊群,顾冬红,&干福熹.(2007).2-氨基-6-乙氧基苯并噻唑类偶氮染料及其金属鏊合物的合成及光学热学性能研究.功能材料,38(5),774.
MLA	陈文忠,et al."2-氨基-6-乙氧基苯并噻唑类偶氮染料及其金属鏊合物的合成及光学热学性能研究".功能材料 38.5(2007):774.