Miscibility and Crystallization Behavior of Poly (Ethylene Terephthalate)/Phosphate Glass Hybrids

	Miscibility and Crystallization Behavior of Poly (Ethylene Terephthalate)/Phosphate Glass Hybrids
	Liu, Huichao 1,2,3; Ma, Jinghong 2; Zhu, Caizhen 1; Xu, Jian 2,3; Gong, Jinghua 2
刊名	JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS
	2016
卷号	55 期号:11 页码:1039-1050
关键词	isothermal crystallization kinetics miscibility phosphate glass poly (ethylene terephthalate) polymer hybrids
英文摘要	Fundamental studies on miscibility and crystallization behavior of poly (ethylene terephthalate) (PET) and inorganic phosphate glass (Pglass) hybrids were conducted. The Flory-Huggins interaction parameter () value of -0.075 for the PET/Pglass hybrids was obtained using the Nishi-Wang equation, demonstrating that the Pglass and PET components were miscible in the melt state. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) showed the phase separation occurred during quenching from the melt. The phase boundaries between PET and Pglass were blurred, which indicated partial compatibility of the components in the solid state. Contact angle measurements indicated the interfacial tension of PET/Pglass hybrids was 1.5mN/m, and the work of adhesion was 78.0mN/m at 28 degrees C. Based on the Hoffman-Lauritzen theory, the nucleation constant (K-g) and fold surface free energy (sigma(e)) of PET/Pglass hybrids were less than those of neat PET.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35143]
专题	化学研究所_高分子物理与化学实验室
作者单位	1.Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518060, Peoples R China 2.Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Liu, Huichao,Ma, Jinghong,Zhu, Caizhen,et al. Miscibility and Crystallization Behavior of Poly (Ethylene Terephthalate)/Phosphate Glass Hybrids[J]. JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS,2016,55(11):1039-1050.
APA	Liu, Huichao,Ma, Jinghong,Zhu, Caizhen,Xu, Jian,&Gong, Jinghua.(2016).Miscibility and Crystallization Behavior of Poly (Ethylene Terephthalate)/Phosphate Glass Hybrids.JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS,55(11),1039-1050.
MLA	Liu, Huichao,et al."Miscibility and Crystallization Behavior of Poly (Ethylene Terephthalate)/Phosphate Glass Hybrids".JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS 55.11(2016):1039-1050.