Highly hydrophilic ultra-high molecular weight polyethylene powder and film prepared by radiation grafting of acrylic acid | |
Wang, HL; Xu, L; Li, R; Pang, LJ; Hu, JT; Wang, MH; Wu, GZ | |
刊名 | APPLIED SURFACE SCIENCE
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2016 | |
卷号 | 382期号:-页码:162—169 |
关键词 | LOW-DENSITY POLYETHYLENE GAMMA-IRRADIATION MECHANICAL-PROPERTIES BEAM IRRADIATION ELECTRON-BEAM BONE-CEMENT ION-BEAMS UHMWPE OXIDATION ADHESION |
ISSN号 | 0169-4332 |
通讯作者 | Wu, GZ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. |
英文摘要 | The surface properties of ultra-high molecular weight polyethylene (UHMWPE) are very important for its use in engineering or composites. In this work, hydrophilic UHMWPE powder and film were prepared by gamma-ray pre-irradiation grafting of acrylic acid (AA) and further neutralization with sodium hydroxide solution. Variations in the chemical structure, grafting yield and hydrophilicity were investigated and compared. FT-IR and XPS analysis results showed that AA was successfully grafted onto UHMWPE powder and film; the powder was more suitable for the grafting reaction in 1 wt% AA solution than the film. Given a dose of 300 kGy, the grafting yield of AA was similar to 5.7% for the powder but similar to 0.8% for the film under identical conditions. Radiation grafting of a small amount of AA significantly improved the hydrophilicity of UHMWPE. The water contact angle of the UHMWPE-g-PAA powder with a grafting yield of AA at similar to 5.7% decreased from 110.2 degrees to 68.2 degrees. Moreover, the grafting powder (UHMWPE-g-PAA) exhibited good dispersion ability in water. (C) 2016 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000376819600021 |
内容类型 | 期刊论文 |
源URL | [http://ir.sinap.ac.cn/handle/331007/25742] ![]() |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
推荐引用方式 GB/T 7714 | Wang, HL,Xu, L,Li, R,et al. Highly hydrophilic ultra-high molecular weight polyethylene powder and film prepared by radiation grafting of acrylic acid[J]. APPLIED SURFACE SCIENCE,2016,382(-):162—169. |
APA | Wang, HL.,Xu, L.,Li, R.,Pang, LJ.,Hu, JT.,...&Wu, GZ.(2016).Highly hydrophilic ultra-high molecular weight polyethylene powder and film prepared by radiation grafting of acrylic acid.APPLIED SURFACE SCIENCE,382(-),162—169. |
MLA | Wang, HL,et al."Highly hydrophilic ultra-high molecular weight polyethylene powder and film prepared by radiation grafting of acrylic acid".APPLIED SURFACE SCIENCE 382.-(2016):162—169. |
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