Synthesis, characterization, and reactivity of a side-on manganese(III)-peroxo complex bearing a pentadentate aminopyridine ligand
Du JY(杜俊毅)1,2; Xu DQ(徐大乾)1; Zhang, Chunxi3; Xia CG(夏春谷)1; Wang Y(王永)1; Sun W(孙伟)1; Sun W(孙伟)
刊名Dalton Transactions
2016
卷号45期号:25页码:10131-10135
ISSN号1477-9226
通讯作者孙伟 ; 王永 ; Zhang, Chunxi
英文摘要

A manganese(II) complex has been prepared with a proline-derived pentadentate ligand (Pro3Py), and it can be converted to a peroxomanganese(III) complex in the presence of H2O2 and triethylamine. The resulting peroxomanganese(III) complex was well characterised by UV-vis, EPR and ESI-MS techniques, and the geometric structure was discussed based on DFT calculations.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the National Natural Science Foundation of China (no. 21473226;21133011;91427303)
语种英语
WOS记录号WOS:000378392200006
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/20123]  
专题兰州化学物理研究所_OSSO国家重点实验室
通讯作者Sun W(孙伟)
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
3.Chinese Acad Sci, Inst Chem, Lab Photochem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Du JY,Xu DQ,Zhang, Chunxi,et al. Synthesis, characterization, and reactivity of a side-on manganese(III)-peroxo complex bearing a pentadentate aminopyridine ligand[J]. Dalton Transactions,2016,45(25):10131-10135.
APA Du JY.,Xu DQ.,Zhang, Chunxi.,Xia CG.,Wang Y.,...&孙伟.(2016).Synthesis, characterization, and reactivity of a side-on manganese(III)-peroxo complex bearing a pentadentate aminopyridine ligand.Dalton Transactions,45(25),10131-10135.
MLA Du JY,et al."Synthesis, characterization, and reactivity of a side-on manganese(III)-peroxo complex bearing a pentadentate aminopyridine ligand".Dalton Transactions 45.25(2016):10131-10135.
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