Spirocyclopropanation Reaction of para-Quinone Methides with Sulfonium Salts: The Synthesis of Spirocyclopropanyl para-Dienones | |
Zhang, Xiang-Zhi1; Du, Ji-Yuan1; Deng, Yu-Hua3; Chu, Wen-Dao1; Yan, Xu1; Yu, Ke-Yin1; Fan, Chun-An1,2 | |
刊名 | Journal of Organic Chemistry |
2016 | |
卷号 | 81期号:6页码:2598-2606 |
ISSN号 | 0022-3263 |
通讯作者 | Fan, Chun-An |
英文摘要 | A novel DBU-mediated stereoselective spirocyclopropanation of para-quinone methides with sulfonium salts has been developed on the basis of the mode involving a 1,6-conjugate addition/intramolecular dearomatizing cyclization cascade. This reaction provides a mild and effective method for the assembly of synthetically and structurally interesting spirocyclopropanyl para-dienones. The feasibility for the enantioselective access to such functionalized para-dienones has also been explored by using the axially chiral sulfonium salt. Importantly, the regioselective ring openings of the related spirocyclopropanyl para-dienones have been achieved divergently. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (21572083;21322201;21290180);the Fundamental Research Funds for the Central Universities (lzujbky-2015-48;lzujbky-2013-ct02);the State Key Laboratory of Natural and Biomimetic Drugs (K20150213);PCSIRT (IRT-15R28);the 111 Project of Ministry of Education of China (111-2-17);Changjiang Scholars Program (C.-A.F.) |
语种 | 英语 |
WOS记录号 | WOS:000372664700038 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/19987] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, 222 Tianshui Nanlu, Lanzhou 730000, Peoples R China 2.Peking Univ, State Key Lab Nat & Biomimet Drugs, 38 Xueyuan Lu, Beijing 100191, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Xiang-Zhi,Du, Ji-Yuan,Deng, Yu-Hua,et al. Spirocyclopropanation Reaction of para-Quinone Methides with Sulfonium Salts: The Synthesis of Spirocyclopropanyl para-Dienones[J]. Journal of Organic Chemistry,2016,81(6):2598-2606. |
APA | Zhang, Xiang-Zhi.,Du, Ji-Yuan.,Deng, Yu-Hua.,Chu, Wen-Dao.,Yan, Xu.,...&Fan, Chun-An.(2016).Spirocyclopropanation Reaction of para-Quinone Methides with Sulfonium Salts: The Synthesis of Spirocyclopropanyl para-Dienones.Journal of Organic Chemistry,81(6),2598-2606. |
MLA | Zhang, Xiang-Zhi,et al."Spirocyclopropanation Reaction of para-Quinone Methides with Sulfonium Salts: The Synthesis of Spirocyclopropanyl para-Dienones".Journal of Organic Chemistry 81.6(2016):2598-2606. |
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