A practical route for the highly stereoselective synthesis of tetrasubstituted fluoroalkenes | |
Cao CR(曹春如); Ou S(欧松); Jiang M(蒋敏); Liu JT(刘金涛) | |
刊名 | Org. Biomol. Chem.
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2014 | |
卷号 | 12期号:3页码:467-473 |
其他题名 | 一种高选择性合成四取代含氟烯烃的实用方法 |
通讯作者 | 刘金涛 |
英文摘要 | A series of tetrasubstituted fluoroatkene derivatives were synthesized by the reaction of alpha-fluoro-beta-carbonyl benzothiazol-2-yl sulfones with various nucleophiles in good yields with high stereoselectivities. The predominant cis configuration of fluorine and alkynyl groups was observed. A single isomer was obtained when a ketone, acetate or amide was used as the substrate in the presence of a base. |
学科主题 | 氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1039/c3ob42093k |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/38832] ![]() |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
作者单位 | 中科院上海有机化学研究所 |
推荐引用方式 GB/T 7714 | Cao CR,Ou S,Jiang M,et al. A practical route for the highly stereoselective synthesis of tetrasubstituted fluoroalkenes[J]. Org. Biomol. Chem.,2014,12(3):467-473. |
APA | 曹春如,欧松,蒋敏,&刘金涛.(2014).A practical route for the highly stereoselective synthesis of tetrasubstituted fluoroalkenes.Org. Biomol. Chem.,12(3),467-473. |
MLA | 曹春如,et al."A practical route for the highly stereoselective synthesis of tetrasubstituted fluoroalkenes".Org. Biomol. Chem. 12.3(2014):467-473. |
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