Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes
	Zheng J(郑军)1; You SL(游书力)1
刊名	Angew. Chem.-Int. Edit.
	2014
卷号	53 期号:48 页码:13244-13247
其他题名	通过铑催化的双芳基化合物与烯烃的不对称脱氢Heck偶联构建轴手性
通讯作者	游书力
英文摘要	Enantioselective construction of axially chiral biaryls by direct C-H bond functionalization reactions has been realized. Novel axially chiral biaryls were synthesized by the direct C-H bond olefination of biaryl compounds, using a chiral [Cp*Rh-III] catalyst, in good to excellent yields and enantioselectivities. The obtained axially chiral biaryls were found as suitable ligands for rhodium-catalyzed asymmetric conjugate additions.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/anie.201408805
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39128]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.中科院上海有机化学研究所 2.天津化学化工协同创新中心
推荐引用方式 GB/T 7714	Zheng J,You SL. Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes[J]. Angew. Chem.-Int. Edit.,2014,53(48):13244-13247.
APA	郑军,&游书力.(2014).Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes.Angew. Chem.-Int. Edit.,53(48),13244-13247.
MLA	郑军,et al."Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes".Angew. Chem.-Int. Edit. 53.48(2014):13244-13247.