Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex

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	Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex
	Wang W(王薇)1; Lv YD(吕英东)1; Gou XF(苟小锋)1; Leng XB(冷雪冰)1; Chen YF(陈耀峰)1
刊名	Chin. J. Chem.
	2014
卷号	32 期号:8 页码:752-756
其他题名	钪膦宾配合物对Pinacolborane 和 Catecholborane 的B-O断裂
通讯作者	苟小锋 ; 陈耀峰
英文摘要	Reactions of bis-scandium bridged phosphinidene complex, [LSc(mu-PAr)](2) (L=MeC(NDIPP)CHC(Me)(NCH2CH2N(Pr-i)(2)), DIPP = 2,6-(Pr-i)(2)C6H3; Ar = 2,6-Me2C6H3) (1), with pinacolborane, catecholborane, and 9-borabicyclo[3.3.1]nonane (9-BBN) are reported. Complex 1 reacts with pinacolborane and catecholborane to give scandium pinacolate (2) and catecholate (3), showing B-O bond cleavage. These two scandium complexes contain an unusual [P(Ar)B(H)P(Ar)](2-) dianion, which displays mu-eta(2)eta(2) coordination model. On the other hand, reaction of complex 1 with 9-BBN affords the B-H bond cleavage product, 1,3-diphospha-2,4-diboracyclobutane (4).
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/cjoc.201400150
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39109]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.西北大学 2.中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Wang W,Lv YD,Gou XF,et al. Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex[J]. Chin. J. Chem.,2014,32(8):752-756.
APA	王薇,吕英东,苟小锋,冷雪冰,&陈耀峰.(2014).Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex.Chin. J. Chem.,32(8),752-756.
MLA	王薇,et al."Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex".Chin. J. Chem. 32.8(2014):752-756.