Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions

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	Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions
	Yang ZP(杨泽鹏); Wu QF(武庆锋); You SL(游书力)
刊名	Angew. Chem.-Int. Edit.
	2014
卷号	53 期号:27 页码:6986-6989
其他题名	通过铱催化的烯丙基胺化反应实现的吡啶和吡嗪的直接不对称去芳构化
通讯作者	游书力
英文摘要	The first iridium-catalyzed intramolecular asymmetric allylic dearomatization reaction of pyridines and pyrazines has been realized. 2,3-Dihydroindolizine and 6,7-dihydropyrrolo[1,2-a]pyrazine derivatives were obtained with excellent yields and enantioselectivity. This methodology features dearomatization by direct N-allylic alkylation of pyridines or pyrazines under mild reaction conditions.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/anie.201404286
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39071]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Yang ZP,Wu QF,You SL. Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions[J]. Angew. Chem.-Int. Edit.,2014,53(27):6986-6989.
APA	杨泽鹏,武庆锋,&游书力.(2014).Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions.Angew. Chem.-Int. Edit.,53(27),6986-6989.
MLA	杨泽鹏,et al."Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions".Angew. Chem.-Int. Edit. 53.27(2014):6986-6989.