Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization

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	Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization
	Xu CJ(许崇杰)1; Chen Z(陈州)1; Shen Q(沈琪)1; Sun XL(孙秀丽)1; Tang Y(唐勇)1
刊名	J. Organomet. Chem.
	2014
卷号	761 页码:142-146
其他题名	beta-羰基亚胺衍生的金属配合物的合成, 表征及其在苯乙烯聚合催化行为的研究
通讯作者	孙秀丽
英文摘要	The titanium and zirconium complexes based on thioether substituted beta-carbonylenamine were prepared and characterized. In the presence of MMAO, the titanium complexes showed good activity in syndiospecific styrene polymerization with high syndioselectivity, and performed good thermal stability. Electron withdrawing group on ligands is beneficial to the styrene polymerization. [1,3-diphenyl-3-(2-(isopropylthio)ethylimino)prop-1-en-1-olate](2)ZrCl2(IV) could also polymerize styrene to give syndiotactic polymer, however in low activity and with low syndioselectivity. (C) 2014 Elsevier B.V. All rights reserved.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.jorganchem.2014.02.021
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39057]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.苏州大学 2.中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Xu CJ,Chen Z,Shen Q,et al. Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization[J]. J. Organomet. Chem.,2014,761:142-146.
APA	许崇杰,陈州,沈琪,孙秀丽,&唐勇.(2014).Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization.J. Organomet. Chem.,761,142-146.
MLA	许崇杰,et al."Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization".J. Organomet. Chem. 761(2014):142-146.