Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity | |
Yang XF(杨晓菲); Li XH(李小惠); Ding CH(丁昌华); Dai LX(戴立信); Hou XL(侯雪龙) | |
刊名 | Chem. Commun.
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2014 | |
卷号 | 50期号:4页码:484-486 |
其他题名 | 钯催化硝基甲烷和二烯基碳酸酯的高C-5位区域选择性的烯丙基烷基化反应 |
通讯作者 | 丁昌华 ; 侯雪龙 |
英文摘要 | A highly regioselective palladium-catalyzed allylic alkylation of dienyl esters with nitromethane has been developed, providing selective access to the C-5 attacked products. The structures of the ligands as well as the steric effect of the substrates are important factors in determining the regiochemical outcome of the reaction. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1039/c3cc46574h |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39023] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
作者单位 | 中科院上海有机化学研究所 |
推荐引用方式 GB/T 7714 | Yang XF,Li XH,Ding CH,et al. Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity[J]. Chem. Commun.,2014,50(4):484-486. |
APA | 杨晓菲,李小惠,丁昌华,戴立信,&侯雪龙.(2014).Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity.Chem. Commun.,50(4),484-486. |
MLA | 杨晓菲,et al."Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity".Chem. Commun. 50.4(2014):484-486. |
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