The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP

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	The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP
	Jiang XY(姜秀玉); Jiang X(江雪); Lu GL(陆国林); Feng C(冯纯); Huang XY(黄晓宇)
刊名	Polym. Chem.
	2014
卷号	5 期号:17 页码:4915-4925
其他题名	The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP
通讯作者	陆国林 ; 黄晓宇
英文摘要	A series of well-defined amphiphilic graft copolymers consisting of a hydrophilic poly(2-hydroxyethyl acrylate) (PHEA) backbone and hydrophobic polystyrene side chains were synthesized by the combination of reversible addition-fragmentation chain transfer (RAFT) polymerization, atom transfer radical polymerization (ATRP), and the grafting-from strategy. A new actylate monomer containing an ATRP initiating group, 2-hydroxyethyl 2-[(2-chloropropanoyloxy)methyl]acrylate, was first prepared via a four-step procedure using 2-hydroxyethyl acrylate as a starting material. This monomer was then RAFT homopolymerized to give a PHEA-based homopolymer bearing a Cl-containing ATRP initiating group in every repeating unit with a narrow molecular weight distribution (M-w/M-n = 1.08). This homopolymer directly initiated the ATRP of styrene to afford the desired well-defined poly(2-hydroxyethyl acrylate)graft-polystyrene graft copolymers (M-w/M-n <= 1.30) containing a hydroxyl in every repeating unit of the backbone without polymeric functionality transformation. The self-assembly behavior of the amphiphilic graft copolymers obtained was investigated by dynamic light scattering and transmission electron microscopy.
学科主题	高分子化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1039/c4py00415a
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/38899]
专题	上海有机化学研究所_高分子材料研究室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Jiang XY,Jiang X,Lu GL,et al. The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP[J]. Polym. Chem.,2014,5(17):4915-4925.
APA	姜秀玉,江雪,陆国林,冯纯,&黄晓宇.(2014).The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP.Polym. Chem.,5(17),4915-4925.
MLA	姜秀玉,et al."The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP".Polym. Chem. 5.17(2014):4915-4925.