STM and XRD studies of the adsorption and assembling structures of phthalocyanine and porphyrin | |
Lei, SB; Wang, J; Dong, YH; Wang, C; Wan, LJ; Bai, CL | |
刊名 | SURFACE AND INTERFACE ANALYSIS |
2002 | |
卷号 | 34期号:1页码:767-771 |
关键词 | STM and XRD studies phthalocyanine porphyrin assembly |
通讯作者 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China ; Chinese Acad Sci, Inst High Energy Phys, Synchrotron Radiat Lab, Beijing 100080, Peoples R China |
英文摘要 | Using scanning tunnelling microscopy (STM) and x-ray diffraction (XRD), the assembling behaviour of substituted phthalocyanine and porphyrin on both hydrophobic and hydrophilic surfaces was investigated. Copper (II) 2,3,9,10,16,17,23,24-octakis(octyloxy)-29H,31H-phthalocyanine (denoted as CuPcOC8) and 21,23-dihydro-5,10,15,20-tetrakis[4-(tetradecyloxy)phenyl]porphyrin (TTPP) molecules adsorb stably on a highly oriented pyrolytic graphite (HOPG) surface, yielding high-resolution STM images. The results illustrate that alkyl molecular anchors can be used as a generalized approach for immobilization of organic molecules on hydrophobic surfaces. The XRD results show that on a hydrophilic substrate CuPcOC8 and TTPP form completely different assembled structures from those on a HOPG surface, which indicates that the polarity of the substrate has substantial effects on the assembling behaviour of organic molecules. Copyright (C) 2002 John Wiley Sons, Ltd. |
学科主题 | Chemistry |
类目[WOS] | Chemistry, Physical |
研究领域[WOS] | Chemistry |
原文出处 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000177885900168 |
内容类型 | 期刊论文 |
源URL | [http://ir.ihep.ac.cn/handle/311005/238450] |
专题 | 高能物理研究所_多学科研究中心 中国科学院高能物理研究所_中国散裂中子源 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Lei, SB,Wang, J,Dong, YH,et al. STM and XRD studies of the adsorption and assembling structures of phthalocyanine and porphyrin[J]. SURFACE AND INTERFACE ANALYSIS,2002,34(1):767-771. |
APA | Lei, SB,Wang, J,Dong, YH,Wang, C,Wan, LJ,&Bai, CL.(2002).STM and XRD studies of the adsorption and assembling structures of phthalocyanine and porphyrin.SURFACE AND INTERFACE ANALYSIS,34(1),767-771. |
MLA | Lei, SB,et al."STM and XRD studies of the adsorption and assembling structures of phthalocyanine and porphyrin".SURFACE AND INTERFACE ANALYSIS 34.1(2002):767-771. |
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