EXAFS and FTIR structural characterization for the crystal of monomeric tetraphenylporphyrinato gadolinium: [Gd(TPP)acac center dot 8H(2)O center dot 3TCB]

	EXAFS and FTIR structural characterization for the crystal of monomeric tetraphenylporphyrinato gadolinium: [Gd(TPP)acac center dot 8H(2)O center dot 3TCB]
	Jiang, JZ; Hu TD(胡天斗); Hu, TD; Xie, JL; Li, C; Zhang, JZ
刊名	CHINESE JOURNAL OF CHEMISTRY
	1998
卷号	16 期号:5 页码:425-429
关键词	EXAFS structure monomeric porphyrinate rare earth
通讯作者	Shandong Univ, Dept Chem, Jinan 250100, Peoples R China ; Acad Sinica, Inst High Energy Phys, Lab Synchrotron Radiat, Beijing 100039, Peoples R China
英文摘要	The coordination number of the gadolinium atom and bond distances in the crystal of monomeric porphyrinate, [Gd(TPP)acac.8H(2)O.3TCB] (TCB: 1,2,4-trichlorobensene, acac: anion of acetylacetone), were determined by EXAFS method. The Gd atom is eight-coordinated to the four nitrogen atoms of a tetraphenylporphyrin ring, to the two oxygen atoms of one acetylacetonato anion and to two water molecules with Gd-N=0.232 nm, Gd-O=0.243 nm.
学科主题	Chemistry
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
原文出处	SCI
语种	英语
WOS记录号	WOS:000076768800006
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/237433]
专题	高能物理研究所_多学科研究中心高能物理研究所_实验物理中心
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Jiang, JZ,Hu TD,Hu, TD,et al. EXAFS and FTIR structural characterization for the crystal of monomeric tetraphenylporphyrinato gadolinium: [Gd(TPP)acac center dot 8H(2)O center dot 3TCB][J]. CHINESE JOURNAL OF CHEMISTRY,1998,16(5):425-429.
APA	Jiang, JZ,胡天斗,Hu, TD,Xie, JL,Li, C,&Zhang, JZ.(1998).EXAFS and FTIR structural characterization for the crystal of monomeric tetraphenylporphyrinato gadolinium: [Gd(TPP)acac center dot 8H(2)O center dot 3TCB].CHINESE JOURNAL OF CHEMISTRY,16(5),425-429.
MLA	Jiang, JZ,et al."EXAFS and FTIR structural characterization for the crystal of monomeric tetraphenylporphyrinato gadolinium: [Gd(TPP)acac center dot 8H(2)O center dot 3TCB]".CHINESE JOURNAL OF CHEMISTRY 16.5(1998):425-429.