Zinc complexes bearing tridentate O,N,O-type half-Salen ligands for ring-opening polymerization of lactide

	Zinc complexes bearing tridentate O,N,O-type half-Salen ligands for ring-opening polymerization of lactide
	Duan,Ranlong; Gao,Bo; Li,Xiang; Pang,Xuan; Wang,Xianhong; Shao,Huili; Chen,Xuesi
刊名	polymer
	2015
卷号	71 期号:9 页码:1-7
关键词	RAC-LACTIDE EPSILON-CAPROLACTONE RACEMIC LACTIDE MECHANISM CATALYSTS KINETICS HOMOPOLYMERIZATION STEREOCONTROL SELECTIVITY KETOIMINES
通讯作者	pang,x
英文摘要	a number of unreported zinc complexes based on tridentate o, n, o-type half-salen ligands were prepared. all the complexes were characterized by h-1, c-13 nmr and elemental analysis. these complexes were used as catalysts with 2-propanol for the ring-opening polymerization of l-lactide and rac-lactide. they were effective in lactide polymerization with good conversions. and polymerizations were living with the narrow molar mass distributions. the bulky substituents with relatively larger steric hindrance of the ligands coordinated to the central metal centers had relatively low polymerizing activity. (c) 2015 elsevier ltd. all rights reserved.
收录类别	SCI
语种	英语
公开日期	2016-05-31
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/67894]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Duan,Ranlong,Gao,Bo,Li,Xiang,et al. Zinc complexes bearing tridentate O,N,O-type half-Salen ligands for ring-opening polymerization of lactide[J]. polymer,2015,71(9):1-7.
APA	Duan,Ranlong.,Gao,Bo.,Li,Xiang.,Pang,Xuan.,Wang,Xianhong.,...&Chen,Xuesi.(2015).Zinc complexes bearing tridentate O,N,O-type half-Salen ligands for ring-opening polymerization of lactide.polymer,71(9),1-7.
MLA	Duan,Ranlong,et al."Zinc complexes bearing tridentate O,N,O-type half-Salen ligands for ring-opening polymerization of lactide".polymer 71.9(2015):1-7.