Linear 3d-4f compounds: synthesis, structure, and determination of the d-f magnetic interaction

	Linear 3d-4f compounds: synthesis, structure, and determination of the d-f magnetic interaction
	Wu,Jianfeng; Zhao,Lang; Zhang,Peng; Zhang,Li; Guoa,Mei; Tang,Jinkui
刊名	dalton transactions
	2015
卷号	44 期号:26 页码:11935-11942
关键词	SINGLE-MOLECULE MAGNETS ANISOTROPY BARRIER GROUND-STATE COMPLEXES RELAXATION CLUSTERS BLOCKING IONS SUBSTITUTION HYSTERESIS
通讯作者	tang,jk
英文摘要	a family of [re2m2l2(ba)(6)] (re = gd, tb, dy, y; m = co, ni, cu, zn; l = 1,2-bis(2-hydroxy-3-methoxybenzylidene)hydrazine; ba = benzoic acid) complexes were synthesized and structurally and magnetically characterized. the magnetic interactions between spin centers were systematically investigated. the interactions of m-m (m = co, ni and cu) and gd-ni/cu were extracted from the fitting of the experimental data of y2m2 (m = co, ni and cu) and gd2m2 (m = ni and cu) derivatives, respectively. furthermore, the ln-m interactions were qualitatively analyzed by deducting the m-m coupling and the contribution of the crystal-field effects of the ln(iii) ion from the total magnetic susceptibility of ln(2)m(2) (ln = dy and tb) compounds. in addition, complex [dy2zn2l2(ba)(6)] shows field induced single molecular magnet behavior profiting from the isolated anisotropic dysprosium ions.
收录类别	SCI
语种	英语
WOS记录号	WOS:000356725000031
公开日期	2016-05-31
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/65164]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Wu,Jianfeng,Zhao,Lang,Zhang,Peng,et al. Linear 3d-4f compounds: synthesis, structure, and determination of the d-f magnetic interaction[J]. dalton transactions,2015,44(26):11935-11942.
APA	Wu,Jianfeng,Zhao,Lang,Zhang,Peng,Zhang,Li,Guoa,Mei,&Tang,Jinkui.(2015).Linear 3d-4f compounds: synthesis, structure, and determination of the d-f magnetic interaction.dalton transactions,44(26),11935-11942.
MLA	Wu,Jianfeng,et al."Linear 3d-4f compounds: synthesis, structure, and determination of the d-f magnetic interaction".dalton transactions 44.26(2015):11935-11942.