Reductive Benzylation of Singly Bonded 1,2,4,15-C-60 Dimers with an Oxazoline or Imidazoline Heterocycle: Unexpected Formation of 1,2,3,16-C-60 Adducts and Insights into the Reactivity of Singly Bonded C-60 Dimers

	Reductive Benzylation of Singly Bonded 1,2,4,15-C-60 Dimers with an Oxazoline or Imidazoline Heterocycle: Unexpected Formation of 1,2,3,16-C-60 Adducts and Insights into the Reactivity of Singly Bonded C-60 Dimers
	Li,Zong-Jun; Li,Shu-Hui; Sun,Tao; Hou,Hui-Lei; Gao,Xiang
刊名	journal of organic chemistry
	2015
卷号	80 期号:7 页码:3566-3571
关键词	SOLAR-CELLS FULLERENE CHEMISTRY AROMATIC NITRILES RADICAL REACTIONS DERIVATIVES FUNCTIONALIZATION ELECTROSYNTHESIS FULLEROOXAZOLES GENERATION HYDROXIDE
通讯作者	gao,x
英文摘要	upon reduction, singly bonded 1,2,4,15-c-60 dimers with an oxazoline or imidazoline heterocycle dissociate into monoanionic 1,2,4-c-60 intermediates, which surprisingly leads to the formation of 1,2,3,16-c-60 rather than 1,2,4,15-c-60 adducts of the original configuration by further benzylation, even though the analogue of dibenzylated c-60 oxazoline with a 1,2,4,15-configuration is stable and has been obtained. these results are corroborated by computational calculations, which rationalize the reaction and clarify the structure of the 1,2,3,16-c-60 adducts, providing new insights into the intrinsic reactivity of singly bonded c-60 dimers.
收录类别	SCI
语种	英语
公开日期	2016-05-31
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/65089]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Li,Zong-Jun,Li,Shu-Hui,Sun,Tao,et al. Reductive Benzylation of Singly Bonded 1,2,4,15-C-60 Dimers with an Oxazoline or Imidazoline Heterocycle: Unexpected Formation of 1,2,3,16-C-60 Adducts and Insights into the Reactivity of Singly Bonded C-60 Dimers[J]. journal of organic chemistry,2015,80(7):3566-3571.
APA	Li,Zong-Jun,Li,Shu-Hui,Sun,Tao,Hou,Hui-Lei,&Gao,Xiang.(2015).Reductive Benzylation of Singly Bonded 1,2,4,15-C-60 Dimers with an Oxazoline or Imidazoline Heterocycle: Unexpected Formation of 1,2,3,16-C-60 Adducts and Insights into the Reactivity of Singly Bonded C-60 Dimers.journal of organic chemistry,80(7),3566-3571.
MLA	Li,Zong-Jun,et al."Reductive Benzylation of Singly Bonded 1,2,4,15-C-60 Dimers with an Oxazoline or Imidazoline Heterocycle: Unexpected Formation of 1,2,3,16-C-60 Adducts and Insights into the Reactivity of Singly Bonded C-60 Dimers".journal of organic chemistry 80.7(2015):3566-3571.