An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines

	An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines
	Zhang, Zhixin 2; Wang, Yehong 1,2; Wang, Min 2; Lu, Jianmin 2; Li, Lihua 2; Zhang, Zhe 2; Li, Mingrun 2; Jiang, Jingyang 1; Wang, Feng 2
刊名	chinese journal of catalysis
	2015-09-01
卷号	36 期号:9 页码:1623-1630
关键词	Ceria Crystal plane effect Oxidative coupling Imine Defect site
英文摘要	we herein report the effects of ceo2 crystal planes on the oxidative coupling of alcohols and amines to form imines. ceo2 exhibits significant catalytic activity under mild reaction conditions (60 degrees c) during the synthesis of 13 different imines, giving >89% conversions and >90% selectivities. the crystal planes of ceo2 greatly affect the catalytic performance. among the crystal planes investigated (the (110), (100) and (111) planes), the (110) plane shows the strongest redox ability and thus the best catalytic activity, generating a 97% yield of the imine at 60 degrees c in 2 h, because it contains the highest concentration of oxygen vacancies. (c) 2015, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, applied ; chemistry, physical ; engineering, chemical
研究领域[WOS]	chemistry ; engineering
关键词[WOS]	one-pot synthesis ; selective synthesis ; gold nanoparticles ; raman-spectroscopy ; tandem synthesis ; low-temperature ; ceria ; catalyst ; oxygen ; secondary
收录类别	SCI
语种	英语
WOS记录号	WOS:000361084300024
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/146524]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Dalian Univ Technol, Fac Chem Environm & Biol Sci & Technol, Coll Chem, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Zhixin,Wang, Yehong,Wang, Min,et al. An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines[J]. chinese journal of catalysis,2015,36(9):1623-1630.
APA	Zhang, Zhixin.,Wang, Yehong.,Wang, Min.,Lu, Jianmin.,Li, Lihua.,...&Wang, Feng.(2015).An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines.chinese journal of catalysis,36(9),1623-1630.
MLA	Zhang, Zhixin,et al."An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines".chinese journal of catalysis 36.9(2015):1623-1630.