Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols

	Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols
	Wang, Qingfu; Du, Wangming; Liu, Tingting; Chai, Huining; Yu, Zhengkun
刊名	tetrahedron letters
	2014-02-26
卷号	55 期号:9 页码:1585-1588
关键词	Ruthenium(II) Pyridyl-imidazolyl-pyrazolyl ligand Oppenauer oxidation Secondary alcohols
通讯作者	余正坤
英文摘要	highly efficient oppenauer-type oxidation of secondary alcohols to the corresponding ketones has been realized by means of the ruthenium(ii) complex catalysts bearing a 2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine ligand. the oxidation reaction underwent in the presence of acetone as oxidant under mild conditions, reaching final tof values up to 3960 h(-1). the hemilability of the ligand is attributed to the high catalytic activity of these ru(ii) complexes. (c) 2014 elsevier ltd. all rights reserved.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	asymmetric transfer hydrogenation ; heterocyclic carbene complexes ; pyrazolyl-imidazolyl ligand ; room-temperature ; ketones ; bearing ; mechanism ; peroxide ; hydride ; green
收录类别	SCI ; CCR
语种	英语
WOS记录号	WOS:000332434000018
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/144204]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Wang, Qingfu,Du, Wangming,Liu, Tingting,et al. Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols[J]. tetrahedron letters,2014,55(9):1585-1588.
APA	Wang, Qingfu,Du, Wangming,Liu, Tingting,Chai, Huining,&Yu, Zhengkun.(2014).Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols.tetrahedron letters,55(9),1585-1588.
MLA	Wang, Qingfu,et al."Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols".tetrahedron letters 55.9(2014):1585-1588.