Supramolecular effects involving the incorporation of guest substrates in imidazolium ionic liquid networks: Recent advances and future developments

CORC > 西双版纳热带植物园 > 中国科学院西双版纳热带植物园 > 文献共享

	Supramolecular effects involving the incorporation of guest substrates in imidazolium ionic liquid networks: Recent advances and future developments
	Leclercq, Loic ; Schmitzer, Andreea R.
刊名	SUPRAMOLECULAR CHEMISTRY
	2009
卷号	21 期号:42433 页码:245-263
关键词	DIELS-ALDER REACTIONS RHODIUM-CATALYZED HYDROFORMYLATION TRANSITION-METAL NANOPARTICLES SOLVATOCHROMIC PROBE BEHAVIOR IONIZATION MASS-SPECTROMETRY FRIEDEL-CRAFTS REACTIONS BAYLIS-HILLMAN REACTION 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE CARBON-DIOXIDE MOLTEN-SALTS
ISSN号	1061-0278
中文摘要	The interest in ionic liquids (ILs) as green solvents has grown enormously in the last few years. ILs have been proved to be convenient and economical solvents due to their efficiencies, non-toxicities and recyclabilities. Logically, these new media are used in a wide range of organic reactions. Recent investigations of the physicochemical properties of imidazolium ILs suggest that they behave as polymeric supramolecules that cannot be seen as conventional solvent. Electrostatic, H-bonds and -stacking interactions occur in imidazolium ILs. When various organic compounds are mixed with imidazolium ILs, 'inclusion complexes' are formed and complex supramolecular organisation is created. In other words, ILs can be seen as a pre-organised medium that can modify the molecular reactivity (selectivity, substrate discrimination, etc.) by the formation of 'inclusion complexes' between guests (reactive species) and the 'host networks' (ILs). This mini review is intended to describe the imidazolium IL organisation (aggregation properties, formation of 'inclusion complexes', etc.) and to underline some of the effects on the organic reactivity of the inclusion of the guest substrates in imidazolium ILs.
学科主题	Chemistry
收录类别	SCI
原文出处	10.1080/10610270802468421
公开日期	2016-05-06
内容类型	期刊论文
源URL	[http://ir.xtbg.org.cn/handle/353005/9763]
专题	西双版纳热带植物园_文献共享
推荐引用方式 GB/T 7714	Leclercq, Loic,Schmitzer, Andreea R.. Supramolecular effects involving the incorporation of guest substrates in imidazolium ionic liquid networks: Recent advances and future developments[J]. SUPRAMOLECULAR CHEMISTRY,2009,21(42433):245-263.
APA	Leclercq, Loic,&Schmitzer, Andreea R..(2009).Supramolecular effects involving the incorporation of guest substrates in imidazolium ionic liquid networks: Recent advances and future developments.SUPRAMOLECULAR CHEMISTRY,21(42433),245-263.
MLA	Leclercq, Loic,et al."Supramolecular effects involving the incorporation of guest substrates in imidazolium ionic liquid networks: Recent advances and future developments".SUPRAMOLECULAR CHEMISTRY 21.42433(2009):245-263.