Superior catalytic performance of Ce1-xBixO2-delta solid solution and Au/Ce1-xBixO2-delta for 5-hydroxymethylfurfural conversion in alkaline aqueous solution

	Superior catalytic performance of Ce1-xBixO2-delta solid solution and Au/Ce1-xBixO2-delta for 5-hydroxymethylfurfural conversion in alkaline aqueous solution
	Miao,Zhenzhen; Zhang,Yibo; Pan,Xiqiang; Wu,Tianxiao; Zhang,Bin; Li,Jingwei; Yi,Ting; Zhang,Zhendong; Yang,Xiangguang
刊名	catalysis science & technology
	2015
卷号	5 期号:2 页码:1314-1322
关键词	SELECTIVE OXIDATION 2 GOLD NANOPARTICLES AEROBIC OXIDATION CERIA NANORODS BENZYL ALCOHOL SUPPORTED GOLD CO OXIDATION LIQUID-PHASE BIOMASS 5-FURANDICARBOXYLIC ACID
通讯作者	miao,zz
英文摘要	porous bi-doped ceria(ce1-xbixo2-delta solid solution) was prepared by the easy citrate method and then used as a supporting material for au nanoparticles (nps) obtained by deposition-precipitation. in the presence of o-2, ce1-xbixo2-delta (0.08 <= x <= 0.5) efficiently catalyzed the conversion of 5-hydroxymethylfurfural (hmf) to 5-hydroxymethyl-2-furancarboxylic acid (hfca) and 2,5-bishydroxymethylfuran (bhmf) in alkaline aqueous solution without degradation of hmf. the excellent catalytic activity was attributed to the oxygen activation and hydride transfer enhanced by bi doping and the large amount of oxygen vacancies. after au nps were supported on ce1-xbixo2-delta (x <= 0.2), the presence of au delta+ facilitated the activation of the c-h bond in the hydroxymethyl group and then the production of 2,5-furandicarboxylic acid (fdca) as an end product, inhibiting the generation of bhmf.
收录类别	SCI
语种	英语
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/64868]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Miao,Zhenzhen,Zhang,Yibo,Pan,Xiqiang,et al. Superior catalytic performance of Ce1-xBixO2-delta solid solution and Au/Ce1-xBixO2-delta for 5-hydroxymethylfurfural conversion in alkaline aqueous solution[J]. catalysis science & technology,2015,5(2):1314-1322.
APA	Miao,Zhenzhen.,Zhang,Yibo.,Pan,Xiqiang.,Wu,Tianxiao.,Zhang,Bin.,...&Yang,Xiangguang.(2015).Superior catalytic performance of Ce1-xBixO2-delta solid solution and Au/Ce1-xBixO2-delta for 5-hydroxymethylfurfural conversion in alkaline aqueous solution.catalysis science & technology,5(2),1314-1322.
MLA	Miao,Zhenzhen,et al."Superior catalytic performance of Ce1-xBixO2-delta solid solution and Au/Ce1-xBixO2-delta for 5-hydroxymethylfurfural conversion in alkaline aqueous solution".catalysis science & technology 5.2(2015):1314-1322.