Effect of Fluorine Substitution on Photovoltaic Properties of Alkoxyphenyl Substituted Benzo[1,2-b:4,5-b']dithiophene-Based Small Molecules | |
Qiu, Beibei1; Yuan, Jun1; Xiao, Xuxian1; He, Dingjun1; Qiu, Lixia1; Zou, Yingping1,2; Zhang, Zhi-guo3; Li, Yongfang3 | |
刊名 | ACS APPLIED MATERIALS & INTERFACES |
2015-11-18 | |
卷号 | 7期号:45页码:25237-25246 |
关键词 | alkoxyphenyl interlayer meta-fluorinated-alkoxyphenyl organic solar cells small molecule photovoltaic materials |
英文摘要 | Two new small molecules, C3T-BDTP and C3T-BDTP-F with alkoxyphenyl-substituted benzo[1,2-b:4,5-b']dithiophene (BDT) and meta-fluorinated-alkoxyphenyl-substituted BDT as the central donor blocks, respectively, have been synthesized and used as donor materials in organic solar cells (OSCs). With the addition of 0.4% v/v 1,8-diiodooctane (DIO), the blend of C3T-BDTP-F/PC71BM showed a higher hole mobility of 8.67 x 10(-4) cm(2))V(-1) s(-1) compared to that of the blend of C3T-BDTP/PC71BM. Two types of interlayers, zirconium acetylacetonate (ZrAcac) and perylene diimide (PDI) derivatives (PDINO and PDIN), were used to further optimize the performance of OSCs. With a device structure of ITO/PEDOT:PSS/donor:PC71BM/PDIN/Al, the OSCs based on C3T-BDTP delivered a satisfying power conversion efficiency (PCE) of 5.27% with an open circuit voltage (Voc) of 0.91 V, whereas the devices based on C3T-BDTP-F showed an enhanced PCE of 5.42% with a higher V-oc of 0.97 V. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-05-09 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/29297] |
专题 | 化学研究所_有机固体实验室 |
作者单位 | 1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China 2.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Qiu, Beibei,Yuan, Jun,Xiao, Xuxian,et al. Effect of Fluorine Substitution on Photovoltaic Properties of Alkoxyphenyl Substituted Benzo[1,2-b:4,5-b']dithiophene-Based Small Molecules[J]. ACS APPLIED MATERIALS & INTERFACES,2015,7(45):25237-25246. |
APA | Qiu, Beibei.,Yuan, Jun.,Xiao, Xuxian.,He, Dingjun.,Qiu, Lixia.,...&Li, Yongfang.(2015).Effect of Fluorine Substitution on Photovoltaic Properties of Alkoxyphenyl Substituted Benzo[1,2-b:4,5-b']dithiophene-Based Small Molecules.ACS APPLIED MATERIALS & INTERFACES,7(45),25237-25246. |
MLA | Qiu, Beibei,et al."Effect of Fluorine Substitution on Photovoltaic Properties of Alkoxyphenyl Substituted Benzo[1,2-b:4,5-b']dithiophene-Based Small Molecules".ACS APPLIED MATERIALS & INTERFACES 7.45(2015):25237-25246. |
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