Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction

	Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction
	Zhou, Jingyuan 1,2; Gao, Xin 1; Liu, Rong 1,2; Xie, Ziqian 1; Yang, Jin 2,3,4; Zhang, Shuqing 1,2; Zhang, Gengmin 3,4; Liu, Huibiao 5; Li, Yuliang 5; Zhang, Jin 1
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2015-06-24
卷号	137 期号:24 页码:7596-7599
英文摘要	Synthesizing graphdiyne with a-well-defined structure is a great challenge. We reported herein a rational approach to synthesize graphdiyne nanowalls using,a modified Glaser-Hay coupling reaction. Hexaethynylbenzene and copper plate were selected as monomer and substrate, respectively. By adjusting, the ratio of added organic alkali along with the amount of Monomer, the proper amount of copper ions was dissolved into the solution, this forming catalytic reaction sites. With a rapid reaction rate of Glaser-Hay coupling, graphdiyne grew vertically at these sites first, and then with more copper ions dissolved, uniform graphdiyne nanowalls formed on the surface of copper substrate: Raman spectra, UV-vis spectra, and HRTEM results' confirmed the features of graphdiyne. These graphdiyne nanowalls also exhibited excellent and stable field-emission properties.
收录类别	SCI
语种	英语
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/27910]
专题	化学研究所_有机固体实验室
作者单位	1.Peking Univ, Coll Chem & Mol Engn, Beijing Sci & Engn Ctr Nanocarbons, Ctr Nanochem,Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Peking Univ, Acad Adv Interdisciplinary Studies, Beijing 100871, Peoples R China 3.Peking Univ, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China 4.Peking Univ, Dept Elect, Beijing 100871, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Jingyuan,Gao, Xin,Liu, Rong,et al. Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2015,137(24):7596-7599.
APA	Zhou, Jingyuan.,Gao, Xin.,Liu, Rong.,Xie, Ziqian.,Yang, Jin.,...&Liu, Zhongfan.(2015).Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,137(24),7596-7599.
MLA	Zhou, Jingyuan,et al."Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 137.24(2015):7596-7599.