Innovative CVD synthesis of Cu2O catalysts for CO oxidation

CORC > 工程热物理研究所 > 中国科学院工程热物理研究所 > 中国科学院工程热物理所（论文库） > 期刊论文（SCI）

	Innovative CVD synthesis of Cu2O catalysts for CO oxidation
	El Kasmi, Achraf 1,2; Tian, Zhen-Yu 2,4; Vieker, Henning 3,5; Beyer, Andre 3; Chafik, Tarik 1
刊名	APPLIED CATALYSIS B-ENVIRONMENTAL
	2016-06-05
卷号	186 页码:10-18
关键词	Catalytic oxidation Carbon monoxide Water effect Pulsed-spray evaporation Chemical vapor deposition
英文摘要	The present work reports on a one-step synthesis of thin Cu2O films deposited at 250 degrees C using pulsed spray evaporation chemical vapor deposition (PSE-CVD). Of interest, water addition (0, 2.5 and 5 vol.%) in the liquid feedstock of Cu(acac)(2) and ethanol was found to have a significant effect on the catalytic performance of these films towards CO oxidation. The obtained films were comprehensively characterized with X-ray diffraction (XRD), Helium ion microscopy (HIM), X-ray photoelectron spectroscopy (XPS) and Ultraviolet-visible (UV-vis) spectrometry. Both the surface composition and optical properties exhibited good correlation with the catalytic activity. The adopted empirical catalytic screening based on light-off curves measurement demonstrated that Cu2O prepared with 5 vol.% of water in the reactant feedstock exhibited the best performance with respect to complete oxidation of CO at 175 degrees C. This finding is reproducible and tentatively attributed to reduced crystallite grain size and more surface oxygen species generated when water was added in the feedstock. Accordingly, the innovative combination of water addition in the feedstock and the use of PSE-CVD technique is expected to assist further synthesis of new efficient thin films paving the way for catalytic applications. (C) 2015 Elsevier B.V. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Physical ; Engineering, Environmental ; Engineering, Chemical
研究领域[WOS]	Chemistry ; Engineering
关键词[WOS]	OXIDE THIN-FILMS ; ELECTRODEPOSITED CUPROUS-OXIDE ; TRANSITION-METAL OXIDES ; LITHIUM-ION BATTERIES ; CARBON-MONOXIDE ; STRUCTURE SENSITIVITY ; CHEMICAL-DEPOSITION ; AU/TIO2 CATALYST ; NANOPARTICLES ; TEMPERATURE
收录类别	SCI
语种	英语
WOS记录号	WOS:000370305900002
公开日期	2016-05-03
内容类型	期刊论文
源URL	[http://ir.etp.ac.cn/handle/311046/112359]
专题	工程热物理研究所_中国科学院工程热物理所（论文库）_期刊论文（SCI）
作者单位	1.Univ Abdelmalek Essaadi, Fac Sci & Tech, Lab LGCVR, BP 416, Tangier, Morocco 2.Univ Bielefeld, Dept Chem, Univ Str 25, D-33615 Bielefeld, Germany 3.Univ Bielefeld, Dept Phys, Univ Str 25, D-33615 Bielefeld, Germany 4.Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China 5.CNM Technol GmbH, D-33609 Bielefeld, Germany
推荐引用方式 GB/T 7714	El Kasmi, Achraf,Tian, Zhen-Yu,Vieker, Henning,et al. Innovative CVD synthesis of Cu2O catalysts for CO oxidation[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2016,186:10-18.
APA	El Kasmi, Achraf,Tian, Zhen-Yu,Vieker, Henning,Beyer, Andre,&Chafik, Tarik.(2016).Innovative CVD synthesis of Cu2O catalysts for CO oxidation.APPLIED CATALYSIS B-ENVIRONMENTAL,186,10-18.
MLA	El Kasmi, Achraf,et al."Innovative CVD synthesis of Cu2O catalysts for CO oxidation".APPLIED CATALYSIS B-ENVIRONMENTAL 186(2016):10-18.