Silicon Phthalocyanine Covalently Functionalized N-Doped Ultrasmall Reduced Graphene Oxide Decorated with Pt Nanoparticles for Hydrogen Evolution from Water

CORC > 苏州纳米技术与纳米仿生研究所 > 中国科学院苏州纳米技术与纳米仿生研究所 > 纳米生物医学与安全研究部 > 张智军团队

	Silicon Phthalocyanine Covalently Functionalized N-Doped Ultrasmall Reduced Graphene Oxide Decorated with Pt Nanoparticles for Hydrogen Evolution from Water
	Huang, J(黄洁); Wu, YJ; Wang, DD; Ma, YF; Yue, ZK; Lu, YT; Zhang, MX; Zhang, ZJ; Yang, P
刊名	ACS APPLIED MATERIALS & INTERFACES
	2015
卷号	7 期号:6 页码:10
关键词	photocatalysis hydrogen evolution N-doped ultrasmall graphene silicon phthalocyanine
通讯作者	Yang, P
英文摘要	To improve the photocatalytic activity of graphene-based catalysts, silicon phthalocyanine (SiPc) covalently functionalized N-doped ultrasmall reduced graphene oxide (N-usRGO) has been synthesized through 1,3-dipolar cycloaddition of azomethine ylides. The obtained product (N-usRGO/SiPc) was characterized by transmission electron microscopy, atomic force microscopy, Fourier transform infrared spectroscopy, Raman spectra, X-ray photoelectron spectroscopy, fluorescence, and UVvis spectroscopy. The results demonstrate that SiPc has been successfully grafted on the surface of N-usRGO. The N-usRGO/SiPc nanocomposite exhibits high light-harvesting efficiency covering a range of wavelengths from the ultraviolet to visible light. The efficient fluorescence quenching and the enhanced photocurrent response confirm that the photoinduced electron transfers from the SiPc moiety to the N-usRGO sheet. Moreover, we chose Pt nanoparticles as cocatalyst to load on N-usRGO/SiPc sheets to obtain the optimal H-2 production effect. The platinized N-usRGO/SiPc (N-usRGO/SiPc/Pt) demonstrates good hydrogen evolution performance under both UVvis and visible light (lambda>400 nm) irradiation. The apparent quantum yields are 1.3% and 0.56% at 365 and 420 nm, respectively. These results reveal that N-usRGO/SiPc/Pt nanocomposite, consolidating the advantages of SiPc, N-usRGO, and Pt NPs, can be a potential candidate for hydrogen evolution from water under UVvis or visible light irradiation.
收录类别	SCI
语种	英语
公开日期	2016-05-03
内容类型	期刊论文
源URL	[http://ir.sinano.ac.cn/handle/332007/3427]
专题	苏州纳米技术与纳米仿生研究所_纳米生物医学与安全研究部_张智军团队
推荐引用方式 GB/T 7714	Huang, J,Wu, YJ,Wang, DD,et al. Silicon Phthalocyanine Covalently Functionalized N-Doped Ultrasmall Reduced Graphene Oxide Decorated with Pt Nanoparticles for Hydrogen Evolution from Water[J]. ACS APPLIED MATERIALS & INTERFACES,2015,7(6):10.
APA	Huang, J.,Wu, YJ.,Wang, DD.,Ma, YF.,Yue, ZK.,...&Yang, P.(2015).Silicon Phthalocyanine Covalently Functionalized N-Doped Ultrasmall Reduced Graphene Oxide Decorated with Pt Nanoparticles for Hydrogen Evolution from Water.ACS APPLIED MATERIALS & INTERFACES,7(6),10.
MLA	Huang, J,et al."Silicon Phthalocyanine Covalently Functionalized N-Doped Ultrasmall Reduced Graphene Oxide Decorated with Pt Nanoparticles for Hydrogen Evolution from Water".ACS APPLIED MATERIALS & INTERFACES 7.6(2015):10.