Influence of the oxygen pressure on the preferred orientation and optical properties of the pulsed-laser deposited Mn1.56Co0.96Ni0.48O4 +/-delta thin films | |
Kong, WW(孔雯雯); Gao, B; Jiang, CP(蒋春萍); Chang, AM | |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
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2015 | |
卷号 | 650页码:6 |
关键词 | Mn1.56Co0.96Ni0.48O4 +/-delta Thin films Preferential orientations Optical properties Raman |
通讯作者 | Chang, AM |
英文摘要 | Mn1.56Co0.96Ni0.48O4 +/-delta (MCN) thin films with different oxygen pressures (in the range of 2 x 10(-4) to 2 Pa) are prepared on Si(100)/SiOx substrates by pulsed laser deposition technique. Effects of oxygen pressures on the microstructure and optical properties of the prepared thin films are investigated in detail. The grain sizes of films gradually decrease and the preferential orientation of the MCN films change from (400) to (113) as the oxygen pressure increases. The x-ray photoelectron spectroscopy results show that the composition of these films is proximity to that of the bulk material. In addition, the Mn3+/Mn4+ pairs increase with an increase in the oxygen pressures increase. From spectroscopic ellipsometer spectroscopy, it is found that both the refractive index n and extinction coefficient k of the (400)-oriented films have no obvious peaks, whereas in the (113)-oriented films, peaks are exist. This feature typically originates from a change in the crystal structure as oxygen pressures increase. Furthermore, the Raman active mode (around ca. 650 cm(-1)) of (400) films almost disappears, whilst the active mode in (113) films remain. (C) 2015 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-05-03 |
内容类型 | 期刊论文 |
源URL | [http://ir.sinano.ac.cn/handle/332007/3275] ![]() |
专题 | 苏州纳米技术与纳米仿生研究所_纳米器件及相关材料研究部_蒋春萍团队 |
推荐引用方式 GB/T 7714 | Kong, WW,Gao, B,Jiang, CP,et al. Influence of the oxygen pressure on the preferred orientation and optical properties of the pulsed-laser deposited Mn1.56Co0.96Ni0.48O4 +/-delta thin films[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2015,650:6. |
APA | Kong, WW,Gao, B,Jiang, CP,&Chang, AM.(2015).Influence of the oxygen pressure on the preferred orientation and optical properties of the pulsed-laser deposited Mn1.56Co0.96Ni0.48O4 +/-delta thin films.JOURNAL OF ALLOYS AND COMPOUNDS,650,6. |
MLA | Kong, WW,et al."Influence of the oxygen pressure on the preferred orientation and optical properties of the pulsed-laser deposited Mn1.56Co0.96Ni0.48O4 +/-delta thin films".JOURNAL OF ALLOYS AND COMPOUNDS 650(2015):6. |
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