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	Troger's Base-Based Microporous Polyimide Membranes for High-Performance Gas Separation
	Jin J(靳健); Wang D(王栋)
刊名	ACS MACRO LETTERS
	2014-07
卷号	3期号:7页码:597-601
关键词	INTRINSIC MICROPOROSITY PERMEATION PROPERTIES TRANSPORT PROPERTIES POLYMERIC MEMBRANES SOLUBLE POLYIMIDES SPIROBIFLUORENE
通讯作者	王栋
英文摘要	It is a great challenge for polyimide to increase its permeability and at the same time to maintain its high selectivity. In this work, Troger's Base (TB)-based polyimides through polymerizing Troger's Base diamines with two kinds of anhydrides were successfully synthesized to enhance the permeability of polyimides for gas separation. The TB-polyirnide membranes exhibited greatly improved gas separation performance for H-2/CH4, H-2/N-2, He/CH4, and CO2/CH4 gas pairs, among which the separation performance of 6-FDA-based TB-polyimides approaches or slightly exceeds the 2008 Robeson upper bound. Our results revealed that the TB unit with rigid and in-built amine structure plays an important role for increasing the permeability of polyimides and simultaneously maintaining high selectivity. In addition, the TB-based polyimide membranes exhibited extremely high solubility selectivity for the CO2/N-2 gas pair up to 62.7 due to a strong affinity between CO2 and nitrogen atoms of tertiary amine in TB.
收录类别	SCI
语种	英语
WOS记录号	WOS:000339226200002
公开日期	2014-12-04
内容类型	期刊论文
源URL	[http://ir.sinano.ac.cn/handle/332007/1647]
专题	苏州纳米技术与纳米仿生研究所_纳米仿生研究部_靳健团队
推荐引用方式 GB/T 7714	Jin J,Wang D. Troger's Base-Based Microporous Polyimide Membranes for High-Performance Gas Separation[J]. ACS MACRO LETTERS,2014,3(7):597-601.
APA	Jin J,&Wang D.(2014).Troger's Base-Based Microporous Polyimide Membranes for High-Performance Gas Separation.ACS MACRO LETTERS,3(7),597-601.
MLA	Jin J,et al."Troger's Base-Based Microporous Polyimide Membranes for High-Performance Gas Separation".ACS MACRO LETTERS 3.7(2014):597-601.

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