One-Step Synthesis of Highly Efficient Nanocatalysts on the Supports with Hierarchical Pores Using Porous Ionic Liquid-Water Gel

	One-Step Synthesis of Highly Efficient Nanocatalysts on the Supports with Hierarchical Pores Using Porous Ionic Liquid-Water Gel
	Kang, XC; Zhang, JL; Shang, WT; Wu, TB; Zhang, P; Han, BX; Wu, ZH; Mo, G; Xing, XQ;吴忠华; Mo G(默广)
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2014
卷号	136 期号:10 页码:3768-3771
英文摘要	Stable porous ionic liquid-water gel induced by inorganic salts was created for the first time. The porous gel was used to develop a one-step method to synthesize supported metal nanocatalysts. Au/SiO2, Ru/SiO2, Pd/Cu(2-pymo)(2) metal-organic framework (Cu-MOF), and Au/polyacrylamide (PAM) were synthesized, in which the supports had hierarchical meso- and macropores, the size of the metal nanocatalysts could be very small (<1 nm), and the size distribution was very narrow even when the metal loading amount was as high as 8 wt %. The catalysts were extremely active, selective, and stable for oxidative esterification of benzyl alcohol to methyl benzoate, benzene hydrogenation to cyclohexane, and oxidation of benzyl alcohol to benzaldehyde because they combined the advantages of the nanocatalysts of small size and hierarchical porosity of the supports. In addition, this method is very simple.
学科主题	Chemistry
收录类别	SCI
WOS记录号	WOS:000332922600015
公开日期	2016-05-03
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/225172]
专题	高能物理研究所_多学科研究中心
推荐引用方式 GB/T 7714	Kang, XC,Zhang, JL,Shang, WT,et al. One-Step Synthesis of Highly Efficient Nanocatalysts on the Supports with Hierarchical Pores Using Porous Ionic Liquid-Water Gel[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2014,136(10):3768-3771.
APA	Kang, XC.,Zhang, JL.,Shang, WT.,Wu, TB.,Zhang, P.,...&邢雪青.(2014).One-Step Synthesis of Highly Efficient Nanocatalysts on the Supports with Hierarchical Pores Using Porous Ionic Liquid-Water Gel.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,136(10),3768-3771.
MLA	Kang, XC,et al."One-Step Synthesis of Highly Efficient Nanocatalysts on the Supports with Hierarchical Pores Using Porous Ionic Liquid-Water Gel".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136.10(2014):3768-3771.