Colouration mechanism of underglaze copper-red decoration porcelain (AD 13th-14th century), China

	Colouration mechanism of underglaze copper-red decoration porcelain (AD 13th-14th century), China
	Zhu, J; Duan, HP; Yang, YM; Guan, L; Xu, W; Chen, DL; Zhang, J; Wang, LH; Huang, YY; Wang, CS;徐伟
刊名	JOURNAL OF SYNCHROTRON RADIATION
	2014
卷号	21 期号:4 页码:751-755
关键词	XANES underglaze copper-red decoration colouration mechanism reflection spectrometry
英文摘要	Underglaze copper-red decoration, i.e. the copper colourant used to paint diversified patterns on the surface of a body and then covered by transparent glaze and fired at high temperature in a reductive firing environment, is famous all over the world. However, the red colouration mechanism generated by underglaze copper remains unclear. In particular, the fact that the edges of the red patterns are orange has been ignored in previous research. Here, non-destructive analysis has been carried out on a precious fragment of early underglaze red porcelain using synchrotron radiation X-ray fluorescence, X-ray absorption near-edge spectroscopy (XANES) and reflection spectrometry techniques. The results suggest that the copper content in the red region is higher than that in the orange region, and other colour generation elements do not have obvious content difference, indicating that the colour generation effect of the underglaze red product is related to the copper content. XANES analysis shows that the valence states of copper in the red and orange regions are similar and metal copper contributes to their hues. The results of reflection spectrometry demonstrate that tiny orange hues could be attributed to the Mie scatting effect. Therefore, light-scattering effects should be considered when researching the colouration mechanism of underglaze red.
学科主题	Instruments & Instrumentation; Optics; Physics
收录类别	SCI
WOS记录号	WOS:000338124300014
公开日期	2016-05-03
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/225169]
专题	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Zhu, J,Duan, HP,Yang, YM,et al. Colouration mechanism of underglaze copper-red decoration porcelain (AD 13th-14th century), China[J]. JOURNAL OF SYNCHROTRON RADIATION,2014,21(4):751-755.
APA	Zhu, J.,Duan, HP.,Yang, YM.,Guan, L.,Xu, W.,...&张静.(2014).Colouration mechanism of underglaze copper-red decoration porcelain (AD 13th-14th century), China.JOURNAL OF SYNCHROTRON RADIATION,21(4),751-755.
MLA	Zhu, J,et al."Colouration mechanism of underglaze copper-red decoration porcelain (AD 13th-14th century), China".JOURNAL OF SYNCHROTRON RADIATION 21.4(2014):751-755.