Immobilization of Lead in Soil Influenced by Soluble Phosphate and Calcium: Lead Speciation Evidence

	Immobilization of Lead in Soil Influenced by Soluble Phosphate and Calcium: Lead Speciation Evidence
	Li, LP; Scheckel, KG; 郑黎荣;Zheng, LR; Liu, GT; Xing, WQ; Xiang, GQ
刊名	JOURNAL OF ENVIRONMENTAL QUALITY
	2014
卷号	43 期号:2 页码:468-474
英文摘要	We investigated the effect of soluble Ca on the speciation of Pb in phosphate-amended soils. A calcareous soil was amended in sequence with soluble phosphate (0 and 299 mg kg(-1) P), calcium nitrate (0, 200, and 400 mg kg(-1) Ca), and/or lead nitrate (0 and 1000 mg kg(-1) Pb) and incubated for 50 d. Extractable Ca was relatively similar across all samples, with a minor reduction in Ca release for treatments amended with P possibly from the formation of Ca-phosphate minerals. Olsen-P extractability from P-added treatments was highest in the non-Pb-amended soils and was about 40% lower when Pb was added as a result of Pb-phosphate formation. In the absence of P, diethylene triamine pentaacetic acid (DTPA)-Pb extractability increased with increasing Ca amendment; however, in the P-amended treatments, DTPA-Pb decreased with increasing Ca addition. X-ray absorption spectroscopy results of the Pb spiked soils indicate that adsorbed Pb is the primary phase (up to 92%) in non-P-amended soils with minor distribution to hydrocerussite and Pb-phosphate phases. In the P-amended treatments, Pb speciation shifted to Pb-phosphate [chloropyromorphite and Pb-3(PO4)(2)] (42-48%) and adsorbed Pb (44-50%). As Ca concentration increased in the P-amended soils, Pb-phosphate speciation moved from combined chloropyromorphite and Pb-3(PO4)(2) (0 mg kg(-1) Ca) to exclusively chloropyromorphite. The study demonstrates that soluble Ca enhances Pb immobilization with P amendments.
学科主题	Environmental Sciences & Ecology
收录类别	SCI
WOS记录号	WOS:000336273200005
公开日期	2016-05-03
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/225080]
专题	高能物理研究所_多学科研究中心
推荐引用方式 GB/T 7714	Li, LP,Scheckel, KG,郑黎荣；Zheng, LR,et al. Immobilization of Lead in Soil Influenced by Soluble Phosphate and Calcium: Lead Speciation Evidence[J]. JOURNAL OF ENVIRONMENTAL QUALITY,2014,43(2):468-474.
APA	Li, LP,Scheckel, KG,郑黎荣；Zheng, LR,Liu, GT,Xing, WQ,&Xiang, GQ.(2014).Immobilization of Lead in Soil Influenced by Soluble Phosphate and Calcium: Lead Speciation Evidence.JOURNAL OF ENVIRONMENTAL QUALITY,43(2),468-474.
MLA	Li, LP,et al."Immobilization of Lead in Soil Influenced by Soluble Phosphate and Calcium: Lead Speciation Evidence".JOURNAL OF ENVIRONMENTAL QUALITY 43.2(2014):468-474.