Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions

	Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions
	Shang, WT; Kang, XC; Ning, H; Zhang, JL; Zhang, XG; Wu, ZH; Mo, G; Xing, XQ; Han, BX;吴忠华; Mo G(默广)
刊名	LANGMUIR
	2013
卷号	29 期号:43 页码:13168-13174
英文摘要	In this work, the La-metal organic frameworks (La-MOFs) were synthesized using lanthanum(III) nitrate and 1,3,5-benzenetricarboxylic acid (BTC) in H2O-in-1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF(6)), bmimPF(6)-in-water, and the bicontinuous microemulsions stabilized by surfactant TX-100. The MOFs prepared were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and FT-IR methods, and the microstructures of the microemulsions in the H2O/bmimPF(6)/TX-100 system were studied by small-angle X-ray scattering (SXAS) technique. It was shown that the dispersed droplets in the water-in-bmimPF(6), bicontinuous and bmimPF6-in-water microemulsions were spherical, lamellar, and cylindrical, respectively. The shapes of the La-MOFs synthesized were similar to that of the droplets in the corresponding microemulsions. This indicated that the morphology of MOFs could be controlled by the microstructures of the microemulsions. On the basis of the systematic experimental results, the mechanism for controlling the morphology of the MOFs was proposed.
学科主题	Chemistry; Materials Science
收录类别	SCI
WOS记录号	WOS:000326429500008
公开日期	2016-05-03
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/224343]
专题	高能物理研究所_多学科研究中心
推荐引用方式 GB/T 7714	Shang, WT,Kang, XC,Ning, H,et al. Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions[J]. LANGMUIR,2013,29(43):13168-13174.
APA	Shang, WT.,Kang, XC.,Ning, H.,Zhang, JL.,Zhang, XG.,...&邢雪青.(2013).Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions.LANGMUIR,29(43),13168-13174.
MLA	Shang, WT,et al."Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions".LANGMUIR 29.43(2013):13168-13174.