Identification of radiolytic products of [C(4)mim][NTf2] and their effects on the Sr2+ extraction

	Identification of radiolytic products of [C(4)mim][NTf2] and their effects on the Sr2+ extraction
	Ao, YY; Peng, J; 袁立永;Yuan, LY; Cui, ZP; Li, C; Li, JQ; Zhai, ML
刊名	DALTON TRANSACTIONS
	2013
卷号	42 期号:12 页码:4299-4305
英文摘要	The trace water-soluble radiolytic products of neat 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide ([C(4)mim][NTf2]) were identified by analysing water-washed samples of.-ray irradiated ionic liquids. CF3SO2OH, CF3SOOH, CF3SO2NH2, HF and H2SO3 were confirmed as main radiolytic products of [C(4)mim][NTf2], and the total radiation chemical yields of the water-soluble radiolytic products (0.35 mu mol J(-1)) and that of hydrogen ions (0.46 +/- 0.02 mu mol J(-1)) were determined by using ion chromatography and neutralization titration, respectively. It was found that the water-soluble radiolytic products of [C(4)mim][NTf2] greatly reduced the extraction efficiency of Sr2+ from water to irradiated [C(4)mim][NTf2], while the waterinsoluble radiolytic products of [C(4)mim][NTf2] had a slight influence on the Sr2+ extraction.
学科主题	Chemistry
收录类别	SCI
WOS记录号	WOS:000315351800026
公开日期	2016-05-03
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/224250]
专题	高能物理研究所_多学科研究中心
推荐引用方式 GB/T 7714	Ao, YY,Peng, J,袁立永；Yuan, LY,et al. Identification of radiolytic products of [C(4)mim][NTf2] and their effects on the Sr2+ extraction[J]. DALTON TRANSACTIONS,2013,42(12):4299-4305.
APA	Ao, YY.,Peng, J.,袁立永；Yuan, LY.,Cui, ZP.,Li, C.,...&Zhai, ML.(2013).Identification of radiolytic products of [C(4)mim][NTf2] and their effects on the Sr2+ extraction.DALTON TRANSACTIONS,42(12),4299-4305.
MLA	Ao, YY,et al."Identification of radiolytic products of [C(4)mim][NTf2] and their effects on the Sr2+ extraction".DALTON TRANSACTIONS 42.12(2013):4299-4305.