Investigation of field emission characteristics and microstructure of nickel-doped DLC nanocomposite films by electrochemical deposition
Wang, Qing1,2; Li, Songli2; Wan SH(万善宏)3
刊名Physica E: Low-dimensional Systems and Nanostructures
2012
卷号46页码:89-96
ISSN号1386-9477
通讯作者Wang, Qing ; 万善宏
英文摘要The as-obtained nickel doped DLC films by the electrochemical process demonstrated the surface morphology of a nano-tip transformed to bumps with increasing nickel compound concentration in the electrolyte, simultaneously the sp2-C content greatly increased. Nickel was incorporated into highly cross-linked amorphous carbon matrix, forming the typical nanocrystalline/amorphous composite microstructure, which was in the form of element nickel, nickel hydroxide, and nickel oxide. Field emission performance showed that nickel incorporation effectively lowers the threshold field from 9.9 to 8.4 V/μm at the electron emission current density of 1 μA/cm2, and greatly increased the emission current density from 21.88 to 163.89 μA/cm2 under 12.455 V/μm for DLC film. The Raman and XPS measurements of the as-deposited films suggested that spatially localized conduction channels formed by the graphite-like sp2-carbon and metallic particles might be responsible for the electron emission in nickel-doped DLC films.
学科主题材料科学与物理化学
收录类别SCI
资助信息the National Natural Science Foundation of China (Grant nos. 50772115;50873047)
语种英语
WOS记录号WOS:000312433400016
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/19316]  
专题兰州化学物理研究所_固体润滑国家重点实验室
作者单位1.Lanzhou Univ Technol, State Key Lab Adv Nonferrous Met Mat, Lanzhou 730050, Peoples R China
2.Lanzhou Univ Technol, Sch Sci, Lanzhou 730050, Gansu, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
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Wang, Qing,Li, Songli,Wan SH. Investigation of field emission characteristics and microstructure of nickel-doped DLC nanocomposite films by electrochemical deposition[J]. Physica E: Low-dimensional Systems and Nanostructures,2012,46:89-96.
APA Wang, Qing,Li, Songli,&Wan SH.(2012).Investigation of field emission characteristics and microstructure of nickel-doped DLC nanocomposite films by electrochemical deposition.Physica E: Low-dimensional Systems and Nanostructures,46,89-96.
MLA Wang, Qing,et al."Investigation of field emission characteristics and microstructure of nickel-doped DLC nanocomposite films by electrochemical deposition".Physica E: Low-dimensional Systems and Nanostructures 46(2012):89-96.
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