Copper-Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl-Substituted Spiro-2H-azirines from 1,6-Enynes

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	Copper-Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl-Substituted Spiro-2H-azirines from 1,6-Enynes
	He, Yu-Tao 1; Wang, Qiang 1; Zhao, Jiahui 1; Wang, Xiao-Zhen 1; Qiu, Yi-Feng 1; Yang, Yu-Chen 1; Hu, Jing-Yuan 1; Liu XY(刘雪原)1; Liang YM(梁永民)1,2
刊名	Advanced Synthesis and Catalysis
	2015
卷号	357 期号:14-15 页码:3069-3075
关键词	2H-azirines cascade cyclization copper enynes spirocyclic skeleton
ISSN号	1615-4150
通讯作者	梁永民
英文摘要	A method for the synthesis of trifluoromethyl CF₃-substituted spirocyclic compounds containing with a unique quaternary carbon center from readily available starting materials has been developed. The reaction provides a facile access to 2H-azirines via cascade cyclization. These compounds constitute a new class of functionalized synthetic intermediates, which can be used for the synthesis of various nitrogen-containing heterocycles and biologically active CF₃-containing compounds.
学科主题	材料科学与物理化学
收录类别	SCI
资助信息	the National Natural Science Foundation (NSF 21272101;21472074;21472073);the Fundamental Research Funds for Central Universities (lzujbky-2014-243);the "111" Project (J1103307);Program for Changjiang Scholars and Innovative Research Team in University (IRT1138);the Cuiying Student Innovation Fund of Lanzhou University (CYCXJJ-2015003)
语种	英语
WOS记录号	WOS:000363507400009
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/19061]
专题	兰州化学物理研究所_固体润滑国家重点实验室
作者单位	1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	He, Yu-Tao,Wang, Qiang,Zhao, Jiahui,et al. Copper-Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl-Substituted Spiro-2H-azirines from 1,6-Enynes[J]. Advanced Synthesis and Catalysis,2015,357(14-15):3069-3075.
APA	He, Yu-Tao.,Wang, Qiang.,Zhao, Jiahui.,Wang, Xiao-Zhen.,Qiu, Yi-Feng.,...&Liang YM.(2015).Copper-Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl-Substituted Spiro-2H-azirines from 1,6-Enynes.Advanced Synthesis and Catalysis,357(14-15),3069-3075.
MLA	He, Yu-Tao,et al."Copper-Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl-Substituted Spiro-2H-azirines from 1,6-Enynes".Advanced Synthesis and Catalysis 357.14-15(2015):3069-3075.