Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3+2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines | |
Zhao, Changgui1; Xie, Xingang1; Duan, Shuangshuang1; Li, Huilin1; Fang, Ran1; She XG(厍学功)1,2 | |
刊名 | Angewandte Chemie International Edition |
2014 | |
卷号 | 53期号:40页码:10789-10793 |
关键词 | cycloaddition gold heterocycles medium-ring compounds synthetic methods |
ISSN号 | 1433-7851 |
英文摘要 | A highly efficient strategy for the formation of medium-sized-ring ethers and amines based on a gold-catalyzed cascade reaction, involving enynyl ester isomerization and intramolecular [3+2] cyclization, has been developed. Various multisubstituted medium-sized-ring unsaturated ethers and amines were obtained through this transformation. This method represents one of the relatively few transition metal catalyzed intramolecular cycloaddition reactions for medium-sized ring synthesis. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the Fundamental Research Funds for MOST (2010CB833200);the NSFC (21125207;21372103;21102062;21203080);SRFDP (20130211110018) |
语种 | 英语 |
WOS记录号 | WOS:000342761500043 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/19248] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Changgui,Xie, Xingang,Duan, Shuangshuang,et al. Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3+2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines[J]. Angewandte Chemie International Edition,2014,53(40):10789-10793. |
APA | Zhao, Changgui,Xie, Xingang,Duan, Shuangshuang,Li, Huilin,Fang, Ran,&She XG.(2014).Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3+2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines.Angewandte Chemie International Edition,53(40),10789-10793. |
MLA | Zhao, Changgui,et al."Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3+2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines".Angewandte Chemie International Edition 53.40(2014):10789-10793. |
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