Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions

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	Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions
	Ke ZG(柯振刚)1,2 ; Zhang Y(张妍)1; Cui XJ(崔新江)1 ; Shi F(石峰)1
刊名	Green Chemistry
	2016
卷号	18 期号:3 页码:808-816
关键词	N-formylation Paraformaldehyde Au/Al2O3 catalyst
ISSN号	1463-9262
通讯作者	石峰
英文摘要	A simple and efficient Au/Al₂O₃ catalyst was prepared by the co-precipitation method for the oxidative N-formylation of amines with paraformaldehyde. Under the optimized reaction conditions, excellent amine conversion and N-formamide selectivity can be obtained with up to 97% yield with water as the solvent under ambient conditions. This catalyst tolerated a wide range of primary amines and second amines, and it can be reused for at least five runs without obvious deactivation.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (21203219);Youth Innovation Promotion Association CAS
语种	英语
WOS记录号	WOS:000369535100029
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/19042]
专题	兰州化学物理研究所_绿色化学研究发展中心兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Ke ZG,Zhang Y,Cui XJ,et al. Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions[J]. Green Chemistry,2016,18(3):808-816.
APA	Ke ZG,Zhang Y,Cui XJ,&Shi F.(2016).Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions.Green Chemistry,18(3),808-816.
MLA	Ke ZG,et al."Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions".Green Chemistry 18.3(2016):808-816.