Surface modification of polytetrafluoroethylene column for two-stationary phase separations by counter-current chromatography

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室

	Surface modification of polytetrafluoroethylene column for two-stationary phase separations by counter-current chromatography
	Quan KJ(全凯军)1,2,3 ; Huang XY(黄新异)1,2 ; Li XT(李晓婷)1,2,3; Wang GH(王高红)1,2,3 ; Liu YJ(刘言娟)1,2,3 ; Duan WD(段文达)1,2,3; Di DL(邸多隆)1,2 ; Di DL(邸多隆)
刊名	Journal of Chromatography A
	2015
卷号	1422 页码:155-162
关键词	CCC Poly-dopamine Auxiliary stationary phase Adsorption Graphene oxide Alkaloid
ISSN号	0021-9673
通讯作者	邸多隆
英文摘要	To improve the separation capability of CCC, a novel solid-liquid two-stationary phases CCC (ASP-CCC) column was prepared employing graphene oxide (GO) conjugated poly-dopamine (PD) coating (GO/PD) as auxiliary stationary phase (ASP). The results of Scanning electron microscopy (SEM), contact angle and X-ray photoelectron spectroscopy (XPS) indicated that nanostructured GO and PD were successfully grafted on the inner wall of the PTFE column. Three alkaloid compounds were selected as the target analytes to evaluate the performance of the novel column. Because of the intermolecular force (hydrogen bond, electrostatic interaction and pi-pi interaction) between the ASP and model compounds, three analytes were well separated with this novel ASP-CCC column. Additionally, the novel column exhibited higher stationary phase retention ratio, about 8%, than original column without changing the chromatographic condition. Furthermore, the eluotropic sequence of analytes on novel column was in accordance with that in the original column. This suggested that the novel column is a CCC column with auxiliary stationary phase (ASP) in its own right, and the present separation mode is the combination of partition chromatography and adsorption chromatography.
学科主题	分析化学与药物化学
收录类别	SCI
资助信息	the National Scientific Foundation of China (NSFC no. 21175142);Open Fund of Key Laboratory of Chemistry of Northwestern Plant Resources of The Chinese Academy of Science (no. CNPR-2011kfkt-02)
语种	英语
WOS记录号	WOS:000365368300017
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/18696]
专题	兰州化学物理研究所_中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室
通讯作者	Di DL(邸多隆)
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Chem Northwestern Plant Resources, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Quan KJ,Huang XY,Li XT,et al. Surface modification of polytetrafluoroethylene column for two-stationary phase separations by counter-current chromatography[J]. Journal of Chromatography A,2015,1422:155-162.
APA	Quan KJ.,Huang XY.,Li XT.,Wang GH.,Liu YJ.,...&邸多隆.(2015).Surface modification of polytetrafluoroethylene column for two-stationary phase separations by counter-current chromatography.Journal of Chromatography A,1422,155-162.
MLA	Quan KJ,et al."Surface modification of polytetrafluoroethylene column for two-stationary phase separations by counter-current chromatography".Journal of Chromatography A 1422(2015):155-162.