Dopamine-mediated fabrication of ultralight graphene aerogels with low volume shrinkage
Li LX(李凌霄)1,2; Li BC(李步成)1; Zhang JP(张俊平)1; Zhang JP(张俊平)
刊名Journal of Materials Chemistry A
2016
卷号4期号:2页码:512-518
ISSN号2050-7488
通讯作者张俊平
英文摘要

Large volume shrinkage and high temperature are frequently encountered problems during the preparation of graphene aerogels via hydrothermal reactions. Here we report the dopamine-mediated fabrication of ultralight graphene aerogels (UGAs) with low volume shrinkage via hydrothermal reactions at low temperature. The UGAs were fabricated by the hydrothermal reaction of the graphene oxide (GO)/dopamine colloidal solutions at 85 degrees C in the presence of dopamine followed by freeze-drying and pyrolysis. The interaction between GO and dopamine in the aqueous phase, the effects of various parameters on the formation of the UGAs, the roles of dopamine in hydrothermal reactions as well as the wettability and electrical conductivity of the UGAs were investigated using a wide range of analytical techniques. The GO concentration, dopamine concentration, and the temperature and time of the hydrothermal reaction have great influences on the formation of the UGAs. The addition of dopamine forms crosslinking points among the GO sheets and results in the partial reduction of GO in the hydrothermal reaction. In addition, the N atoms of dopamine were doped into the graphene sheets. The UGAs feature low volume shrinkage (8.3%), ultralow density (3.5 mg cm-3), excellent superhydrophobicity/superoleophilicity (CA(water) similar to 155.5 degrees and CA(oil) similar to 0 degrees), very high absorbency for organic liquids (134.0-282.9 g g-1) as well as excellent fire retardant properties and high conductivity (3.07 S cm-1). All these merits make the UGAs very promising materials for absorption of organic pollutants, sensors, energy storage, etc.

学科主题环境材料与生态化学
收录类别SCI
资助信息the “Hundred Talents Program” of the Chinese Academy of Sciences;the National Natural Science Foundation (51503212)
语种英语
WOS记录号WOS:000367272800021
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/18966]  
专题兰州化学物理研究所_环境材料与生态化学研究发展中心
兰州化学物理研究所_OSSO国家重点实验室
通讯作者Zhang JP(张俊平)
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Ecomat & Green Chem, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Li LX,Li BC,Zhang JP,et al. Dopamine-mediated fabrication of ultralight graphene aerogels with low volume shrinkage[J]. Journal of Materials Chemistry A,2016,4(2):512-518.
APA Li LX,Li BC,Zhang JP,&张俊平.(2016).Dopamine-mediated fabrication of ultralight graphene aerogels with low volume shrinkage.Journal of Materials Chemistry A,4(2),512-518.
MLA Li LX,et al."Dopamine-mediated fabrication of ultralight graphene aerogels with low volume shrinkage".Journal of Materials Chemistry A 4.2(2016):512-518.
个性服务
查看访问统计
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。


©版权所有 ©2017 CSpace - Powered by CSpace